Transition metal-based catalysts for the electrochemical CO 2 reduction: from atoms and molecules to nanostructured materials

F Franco, C Rettenmaier, HS Jeon… - Chemical Society …, 2020 - pubs.rsc.org
The electrochemical reduction of carbon dioxide (CO2) powered by renewable energy is an
attractive sustainable approach to mitigate CO2 emissions and to produce fuels or value …

Challenges and recent advancements in the transformation of CO 2 into carboxylic acids: straightforward assembly with homogeneous 3d metals

R Cauwenbergh, V Goyal, R Maiti, K Natte… - Chemical Society …, 2022 - pubs.rsc.org
The transformation of carbon dioxide (CO2) into useful chemicals, advanced materials, and
energy is a long-standing challenge in both fundamental science and industry. In recent …

Electro-and solar-driven fuel synthesis with first row transition metal complexes

KE Dalle, J Warnan, JJ Leung, B Reuillard… - Chemical …, 2019 - ACS Publications
The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

Transition Metal Complexes as Catalysts for the Electroconversion of CO2: An Organometallic Perspective

NW Kinzel, C Werlé, W Leitner - … Chemie International Edition, 2021 - Wiley Online Library
The electrocatalytic transformation of carbon dioxide has been a topic of interest in the field
of CO2 utilization for a long time. Recently, the area has seen increasing dynamics as an …

Homogeneously catalyzed electroreduction of carbon dioxide—methods, mechanisms, and catalysts

R Francke, B Schille, M Roemelt - Chemical reviews, 2018 - ACS Publications
The utilization of CO2 via electrochemical reduction constitutes a promising approach
toward production of value-added chemicals or fuels using intermittent renewable energy …

Electrocatalytic metal hydride generation using CPET mediators

S Dey, F Masero, E Brack, M Fontecave, V Mougel - Nature, 2022 - nature.com
Transition metal hydrides (MH) are ubiquitous intermediates in a wide range of enzymatic
processes and catalytic reactions, playing a central role in H+/H2 interconversion, the …

Molecular engineering of metal complexes for electrocatalytic carbon dioxide reduction: From adjustment of intrinsic activity to molecular immobilization

ZW Yang, JM Chen, LQ Qiu, WJ Xie… - Angewandte Chemie …, 2022 - Wiley Online Library
The electrocatalytic CO2 reduction reaction (ECO2RR) is one promising method for storing
intermittent clean energy in chemical bonds and producing fuels. Among various kinds of …

Decoding the CO2 Reduction Mechanism of a Highly Active Organometallic Manganese Electrocatalyst: Direct Observation of a Hydride Intermediate and Its …

S Fernández, F Franco, M Martínez Belmonte… - ACS …, 2023 - ACS Publications
A detailed mechanistic study of the electrochemical CO2 reduction catalyzed by the fac-[MnI
(CO) 3 (bis-MeNHC) MeCN]+ complex (1-MeCN+) is reported herein by combining in situ …

Ligand-controlled product selectivity in electrochemical carbon dioxide reduction using manganese bipyridine catalysts

MH Rønne, D Cho, MR Madsen… - Journal of the …, 2020 - ACS Publications
Electrocatalysis is a promising tool for utilizing carbon dioxide as a feedstock in the chemical
industry. However, controlling the selectivity for different CO2 reduction products remains a …

Tuning Product Selectivity for Aqueous CO2 Reduction with a Mn(bipyridine)-pyrene Catalyst Immobilized on a Carbon Nanotube Electrode

B Reuillard, KH Ly, TE Rosser… - Journal of the …, 2017 - ACS Publications
The development of high-performance electrocatalytic systems for the controlled reduction of
CO2 to value-added chemicals is a key goal in emerging renewable energy technologies …