Transformations of less-activated phenols and phenol derivatives via C–O cleavage
Employing phenols and phenol derivatives as electrophiles for cross-coupling reactions has
numerous advantages over commonly used aryl halides in terms of environmental …
numerous advantages over commonly used aryl halides in terms of environmental …
Advances in synthetic applications of hypervalent iodine compounds
A Yoshimura, VV Zhdankin - Chemical reviews, 2016 - ACS Publications
The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …
Photoredox-enabled dearomative [2π+ 2σ] cycloaddition of phenols
S Dutta, D Lee, K Ozols, CG Daniliuc… - Journal of the …, 2024 - ACS Publications
Dearomative photocycloaddition of monocyclic arenes is an appealing strategy for
comprehending the concept of “escape from flatland”. This brings the replacement of readily …
comprehending the concept of “escape from flatland”. This brings the replacement of readily …
Recent advances in chemical dearomatization of nonactivated arenes
WC Wertjes, EH Southgate, D Sarlah - Chemical Society Reviews, 2018 - pubs.rsc.org
Dearomatization reactions provide a synthetic connection between readily available, simple
aromatic starting materials and more saturated intermediates of greater molecular …
aromatic starting materials and more saturated intermediates of greater molecular …
Sequential and direct multicomponent reaction (MCR)-based dearomatization strategies
Dearomatization strategies in a multicomponent fashion often result in complex heterocyclic
frameworks, which have attracted the attention of chemists due to their natural product-like …
frameworks, which have attracted the attention of chemists due to their natural product-like …
Catalytic asymmetric dearomatization reactions
CX Zhuo, W Zhang, SL You - … Chemie International Edition, 2012 - Wiley Online Library
This Review summarizes the development of catalytic asymmetric dearomatization (CADA)
reactions. The CADA reactions discussed herein include oxidative dearomatization …
reactions. The CADA reactions discussed herein include oxidative dearomatization …
Cyclic hypervalent iodine reagents for atom‐transfer reactions: beyond trifluoromethylation
Hypervalent iodine compounds are privileged reagents in organic synthesis because of their
exceptional reactivity. Among these compounds, cyclic derivatives stand apart because of …
exceptional reactivity. Among these compounds, cyclic derivatives stand apart because of …
Dearomatization strategies in the synthesis of complex natural products
SP Roche, JA Porco Jr - Angewandte Chemie International …, 2011 - Wiley Online Library
Evolution in the field of the total synthesis of natural products has led to exciting
developments over the last decade. Numerous chemoselective and enantioselective …
developments over the last decade. Numerous chemoselective and enantioselective …
Chiral hypervalent iodines: active players in asymmetric synthesis
A Parra - Chemical reviews, 2019 - ACS Publications
Asymmetric organocatalytic oxidations have been witnessed to an impressive development
in the last years thanks to the establishment of important chiral hypervalent iodines (III/V) …
in the last years thanks to the establishment of important chiral hypervalent iodines (III/V) …
[HTML][HTML] Shaping molecular landscapes: recent advances, opportunities, and challenges in dearomatization
CJ Huck, D Sarlah - Chem, 2020 - cell.com
Dearomatization is a fundamental chemical transformation, and it underlies some of the
most efficient tactics for generating three-dimensional complexity from basic two …
most efficient tactics for generating three-dimensional complexity from basic two …