Transition Metal Complexes as Catalysts for the Electroconversion of CO2: An Organometallic Perspective

NW Kinzel, C Werlé, W Leitner - … Chemie International Edition, 2021 - Wiley Online Library
The electrocatalytic transformation of carbon dioxide has been a topic of interest in the field
of CO2 utilization for a long time. Recently, the area has seen increasing dynamics as an …

Understanding the Role of Inter- and Intramolecular Promoters in Electro- and Photochemical CO2 Reduction Using Mn, Re, and Ru Catalysts

E Fujita, DC Grills, GF Manbeck… - Accounts of Chemical …, 2022 - ACS Publications
Conspectus Recycling of carbon dioxide to fuels and chemicals is a promising strategy for
renewable energy storage. Carbon dioxide conversion can be achieved by (i) artificial …

Earth-Abundant Photocatalytic CO2 Reduction by Multielectron Chargeable Cobalt Porphyrin Catalysts: High CO/H2 Selectivity in Water Based on Phase Mismatch …

X Zhang, K Yamauchi, K Sakai - ACS Catalysis, 2021 - ACS Publications
To stop global warming and climate changes, substantial efforts have been made to
diminish CO2 emission. Photocatalytic and electrocatalytic CO2 reduction into fuels has thus …

Secondary-Sphere Effects in Molecular Electrocatalytic CO2 Reduction

AW Nichols, CW Machan - Frontiers in chemistry, 2019 - frontiersin.org
The generation of fuels and value-added chemicals from carbon dioxide (CO2) using
electrocatalysis is a promising approach to the eventual large-scale utilization of intermittent …

Enhanced Electrochemical CO2 Reduction by a Series of Molecular Rhenium Catalysts Decorated with Second-Sphere Hydrogen-Bond Donors

K Talukdar, S Sinha Roy, E Amatya… - Inorganic …, 2020 - ACS Publications
A series of rhenium (I) fac-tricarbonyl complexes containing pendent arylamine functionality
in the second coordination sphere have been developed and studied as electrocatalysts for …

Rhenium chemistry–then and now

JR Dilworth - Coordination Chemistry Reviews, 2021 - Elsevier
The first section provides a background to the whole review. The second presents a
historical perspective of fundamental developments in rhenium chemistry from its discovery …

Manganese and Rhenium Tricarbonyl Complexes Equipped with Proton Relays in the Electrochemical CO2 Reduction Reaction

J Mukherjee, I Siewert - European Journal of Inorganic …, 2020 - Wiley Online Library
The minireview focuses on the electrochemical CO2 reduction catalysed by manganese and
rhenium tricarbonyl complexes with α‐diimine ligands having pendant proton relays …

Rhenium Complexes of Pyridyl-Mesoionic Carbenes: Photochemical Properties and Electrocatalytic CO2 Reduction

L Suntrup, F Stein, J Klein, A Wilting… - Inorganic …, 2020 - ACS Publications
Mesoionic carbenes have found wide use as components of homogeneous catalysts.
Recent discoveries have, however, shown that metal complexes of such ligands also have …

Rhenium bipyridine catalysts with hydrogen bonding pendant amines for CO 2 reduction

AN Hellman, R Haiges, SC Marinescu - Dalton Transactions, 2019 - pubs.rsc.org
Rhenium tricarbonyl bipyridine complexes modified with pendant secondary and tertiary
amines in the 6-and 6′-positions were synthesized and characterized. Electrocatalytic …

Alternating Metal‐Ligand Coordination Improves Electrocatalytic CO2 Reduction by a Mononuclear Ru Catalyst**

H Agarwala, X Chen, JR Lyonnet… - Angewandte …, 2023 - Wiley Online Library
Molecular electrocatalysts for CO2‐to‐CO conversion often operate at large overpotentials,
due to the large barrier for C− O bond cleavage. Illustrated with ruthenium polypyridyl …