Abstract The ligands 3, 6‐di (pyridin‐4‐yl)‐1, 4‐dihydro‐1, 2, 4, 5‐tetrazine (H2DPT), as a
pillar spacer, and 4, 4′‐oxybis (benzoic acid)(H2OBA), as a dicarboxylate linker, have …

The organization of a Zn-based metal–organic framework (MOF) as the first solvent
switching catalyst has been achieved via in situ ligand incorporation. The catalytic …

The density functional theory (DFT) method has been used to study the electronic
communication in strongly interacting oxo-bridged di-{MoII, I (NO+)} 3+, 2+ complexes …

A combined action of the C–H⋯ Oalkoxide hydrogen bonding and Cl⋯ πpyrazolyl dispersive
interactions facilitates intramolecular electron transfer (ET) in the transient {MoI …

Two cases of mediated electron transfer are presented: chloroform reduction catalysed by
Mo II/I alkoxy scorpionates and debromination of hexabromocyclododecane (HBCD) in the …

Previously we reported on the catalytic properties of species based on the {Mo (NO)(TpMe2)
O2} moiety in the cathodic reduction of chloroform. Here, we have performed cyclic …

The redox-active doubly bridged species [{Mo (NO)(TpMe2) Q} 2][TpMe2= tris (3, 5-
dimethylpyrazol-1-yl) hydroborate, Q= O (CH2) nO, n= 3, 5, or OCH2 (CF2) n− 2CH2O, n= 5 …

Our environment and lives have been seriously influenced by anthropogenic CO2
emissions. The Intergovernmental Panel on Climate Change (IPCC) reported that the …

The unusual 18e seven-coordinate Mo (II) complex [Mo (NO)(H2NO-κ2N, O)(TpMe2)
I](1;[TpMe2]− is hydrotris (3, 5-dimethylpyrazol-1-yl) borate) has been synthesised and …

Związki o mieszanej wartościowości są dobrymi modelami do badań nad zjawiskiem
transferu elektronu. W zależności od układu niesparowany elektron może być …