Two acyclic tetradentate Schiff base ligands, HLX–OH (X= H and Br), were synthesised by 2:
1 condensation of either 2-pyridinecarboxaldehyde or 5-bromo-2-pyridinecarboxaldehyde …

Spin crossover (SCO) complexes, which exhibit changes in spin state in response to
external stimuli, have applications in molecular electronics and are challenging materials for …

The iron (II)[2× 2] grid complex Fe-8H has been synthesized and characterized. It undergoes
spin-crossover (SCO) upon deprotonation of the hydrazine-based terpyridine-like ligand …

The transition between spin states in d-block metal complexes has important ramifications
for their structure and reactivity, with applications ranging from information storage materials …

The utilization of spin crossover (SCO) to modulate the luminescence properties in smart
multifunctional materials and multichannel sensors is promising. However, it is challenging …

A new synthetic pathway is devised to selectively produce previously elusive heteroleptic
iron (II) complexes of terpyridine and N, N′-disubstituted bis (pyrazol-3-yl) pyridines that …

We report the multi-step synthesis of the tetradentate 2-(naphthalen-2-yl)-5-[N, N-bis (2-
pyridylmethyl) aminomethyl]-1, 3, 4-oxadiazole ligand (LTetra-ODA) along with its …

Here, we report a combined study of the effects of two chemical modifications to an N, N′-
disubstituted bis (pyrazol-3-yl) pyridine (3-bpp) and of different solvents on the spin …

Two new cyano-bridged mixed-valence {FeIII2 (μ-CN) 4FeII2} clusters,{[(Tp) FeIII (CN) 3] 2
[FeII (Py2N2)] 2}·(ClO4) 2· MeCN· Et2O (1· MeCN· Et2O), its solvent-free form (1), and {[(Tp) …

Two isomeric pyrimidine-based Rdpt-type triazole ligands were made: 4-(4-methylphenyl)-3-
(2-pyrimidyl)-5-phenyl-4 H-1, 2, 4-triazole (L 2pyrimidine) and 4-(4-methylphenyl)-3-(4 …