Nonclassical Applications of closo-Carborane Anions: From Main Group Chemistry and Catalysis to Energy Storage
Classically closo-carborane anions, particularly [HCB11H11]− and [HCB9H9]−, and their
derivatives have primarily been used as weakly coordinating anions to isolate reactive …
derivatives have primarily been used as weakly coordinating anions to isolate reactive …
Transition metal complexes with carboranylphosphine ligands
IB Sivaev, MY Stogniy, VI Bregadze - Coordination Chemistry Reviews, 2021 - Elsevier
Synthesis and structure of transition metal complexes with phosphine ligands derived from
icosahedral dicarbaboranes C 2 B 10 H 12, monocarbaboranes [CB 9 H 10]− and [CB 11 H …
icosahedral dicarbaboranes C 2 B 10 H 12, monocarbaboranes [CB 9 H 10]− and [CB 11 H …
Functional group directed B–H activation of polyhedral boron hydrides by transition metal complexes
IB Sivaev - Russian Journal of Inorganic Chemistry, 2021 - Springer
Activation of B–H groups of polyhedral boron hydrides (boranes and carboranes) is one of
the most actively developing areas of boron chemistry and is of considerable interest for …
the most actively developing areas of boron chemistry and is of considerable interest for …
Blue Phosphorescent Zwitterionic Iridium(III) Complexes Featuring Weakly Coordinating nido-Carborane-Based Ligands
JC Axtell, KO Kirlikovali, PI Djurovich… - Journal of the …, 2016 - ACS Publications
We report the development of a new class of phosphorescent zwitterionic bis (heteroleptic) Ir
(III) compounds containing pyridyl ligands with weakly coordinating nido-carboranyl …
(III) compounds containing pyridyl ligands with weakly coordinating nido-carboranyl …
An Iridium-Stabilized Borenium Intermediate
M Hamdaoui, F Liu, Y Cornaton, X Lu… - Journal of the …, 2022 - ACS Publications
Exploration of new organometallic systems based on polyhedral boron clusters has the
potential to solve challenging chemical problems such as the stabilization of reactive …
potential to solve challenging chemical problems such as the stabilization of reactive …
-carboryne complex of ruthenium: synthesis by double B–H activation at a single metal center
BJ Eleazer, MD Smith, AA Popov… - Journal of the American …, 2016 - ACS Publications
The first example of a transition metal (BB)-carboryne complex containing two boron atoms
of the icosahedral cage connected to a single exohedral metal center (POBBOP) Ru (CO) 2 …
of the icosahedral cage connected to a single exohedral metal center (POBBOP) Ru (CO) 2 …
Teaching an old dog new tricks: new directions in fundamental and applied closo-carborane anion chemistry
This feature article covers new directions in the fundamental and applied chemistry of the
closo-carborane anions [HCB11H11]− and [HCB9H9]−, as well as some related chemistry …
closo-carborane anions [HCB11H11]− and [HCB9H9]−, as well as some related chemistry …
Fusing N‐heterocyclic carbenes with carborane anions
A El‐Hellani, V Lavallo - Angewandte Chemie, 2014 - Wiley Online Library
Here we describe the fusion of two families of unusual carbon‐containing molecules that
readily disregard the tendency of carbon to form four chemical bonds, namely N …
readily disregard the tendency of carbon to form four chemical bonds, namely N …
Cation reduction and comproportionation as novel strategies to produce high voltage, halide free, carborane based electrolytes for rechargeable Mg batteries
Here we describe the cation reduction and comproportionation as novel routes to synthesize
electrolytes for rechargeable Mg-ion batteries. Reduction of the ammonium cation in …
electrolytes for rechargeable Mg-ion batteries. Reduction of the ammonium cation in …
Recent advances in B–H functionalization of icosahedral carboranes and boranes by transition metal catalysis
S Duttwyler - Pure and Applied Chemistry, 2018 - degruyter.com
Significant progress in the functionalization of icosahedral boron clusters has been made in
the past years, leading to an increasing number of applications in various fields of research …
the past years, leading to an increasing number of applications in various fields of research …