Nonclassical Applications of closo-Carborane Anions: From Main Group Chemistry and Catalysis to Energy Storage

SP Fisher, AW Tomich, SO Lovera… - Chemical …, 2019 - ACS Publications
Classically closo-carborane anions, particularly [HCB11H11]− and [HCB9H9]−, and their
derivatives have primarily been used as weakly coordinating anions to isolate reactive …

Transition metal complexes with carboranylphosphine ligands

IB Sivaev, MY Stogniy, VI Bregadze - Coordination Chemistry Reviews, 2021 - Elsevier
Synthesis and structure of transition metal complexes with phosphine ligands derived from
icosahedral dicarbaboranes C 2 B 10 H 12, monocarbaboranes [CB 9 H 10]− and [CB 11 H …

Functional group directed B–H activation of polyhedral boron hydrides by transition metal complexes

IB Sivaev - Russian Journal of Inorganic Chemistry, 2021 - Springer
Activation of B–H groups of polyhedral boron hydrides (boranes and carboranes) is one of
the most actively developing areas of boron chemistry and is of considerable interest for …

Blue Phosphorescent Zwitterionic Iridium(III) Complexes Featuring Weakly Coordinating nido-Carborane-Based Ligands

JC Axtell, KO Kirlikovali, PI Djurovich… - Journal of the …, 2016 - ACS Publications
We report the development of a new class of phosphorescent zwitterionic bis (heteroleptic) Ir
(III) compounds containing pyridyl ligands with weakly coordinating nido-carboranyl …

An Iridium-Stabilized Borenium Intermediate

M Hamdaoui, F Liu, Y Cornaton, X Lu… - Journal of the …, 2022 - ACS Publications
Exploration of new organometallic systems based on polyhedral boron clusters has the
potential to solve challenging chemical problems such as the stabilization of reactive …

-carboryne complex of ruthenium: synthesis by double B–H activation at a single metal center

BJ Eleazer, MD Smith, AA Popov… - Journal of the American …, 2016 - ACS Publications
The first example of a transition metal (BB)-carboryne complex containing two boron atoms
of the icosahedral cage connected to a single exohedral metal center (POBBOP) Ru (CO) 2 …

Teaching an old dog new tricks: new directions in fundamental and applied closo-carborane anion chemistry

SP Fisher, AW Tomich, J Guo, V Lavallo - Chemical Communications, 2019 - pubs.rsc.org
This feature article covers new directions in the fundamental and applied chemistry of the
closo-carborane anions [HCB11H11]− and [HCB9H9]−, as well as some related chemistry …

Fusing N‐heterocyclic carbenes with carborane anions

A El‐Hellani, V Lavallo - Angewandte Chemie, 2014 - Wiley Online Library
Here we describe the fusion of two families of unusual carbon‐containing molecules that
readily disregard the tendency of carbon to form four chemical bonds, namely N …

Cation reduction and comproportionation as novel strategies to produce high voltage, halide free, carborane based electrolytes for rechargeable Mg batteries

SG McArthur, L Geng, J Guo, V Lavallo - Inorganic Chemistry Frontiers, 2015 - pubs.rsc.org
Here we describe the cation reduction and comproportionation as novel routes to synthesize
electrolytes for rechargeable Mg-ion batteries. Reduction of the ammonium cation in …

Recent advances in B–H functionalization of icosahedral carboranes and boranes by transition metal catalysis

S Duttwyler - Pure and Applied Chemistry, 2018 - degruyter.com
Significant progress in the functionalization of icosahedral boron clusters has been made in
the past years, leading to an increasing number of applications in various fields of research …