Polymer sensors for nitroaromatic explosives detection

SJ Toal, WC Trogler - Journal of Materials Chemistry, 2006 - pubs.rsc.org
Several polymers have been used to detect nitroaromatic explosives by a variety of
transduction schemes. Detection relies on both electronic and structural interactions …

Detection of nitroaromatic explosives based on photoluminescent polymers containing metalloles

H Sohn, MJ Sailor, D Magde… - Journal of the American …, 2003 - ACS Publications
The synthesis, spectroscopic characterization, and fluorescence quenching efficiency of
polymers and copolymers containing tetraphenylsilole or tetraphenylgermole with Si− Si …

Cross-coupling reactions in the chemistry of silole-containing π-conjugated oligomers and polymers

S Yamaguchi, K Tamao - Journal of organometallic chemistry, 2002 - Elsevier
Various types of silole-containing π-conjugated oligomers and polymers, including the silole–
pyrrole cooligomers, silole–diethynylarene copolymers, silole–arene alternating copolymers …

Detection of TNT and picric acid on surfaces and in seawater by using photoluminescent polysiloles

H Sohn, RM Calhoun, MJ Sailor… - Angewandte Chemie …, 2001 - Wiley Online Library
Polysilanes exhibit high hole mobility and high nonlinear optical susceptibility in the UV
region which makes them efficient photoemission candidates for a variety of optoelectronics …

Synthesis, luminescence properties, and explosives sensing with 1, 1-tetraphenylsilole-and 1, 1-silafluorene-vinylene polymers

JC Sanchez, AG DiPasquale, AL Rheingold… - Chemistry of …, 2007 - ACS Publications
The syntheses, spectroscopic characterizations, and fluorescence quenching efficiencies of
polymers and copolymers containing tetraphenylsilole-or silafluorene-vinylene repeat units …

Nano-scale charge trapping memory based on two-dimensional conjugated microporous polymer

A Rezk, MHR Ansari, KC Ranjeesh, S Gaber… - Scientific Reports, 2023 - nature.com
There is a growing interest in new semiconductor nanostructures for future high-density high-
performance flexible electronic devices. Two-dimensional conjugated microporous polymers …

Siloles: Part 1: Synthesis, characterization, and applications

JY Corey - Advances in Organometallic Chemistry, 2011 - Elsevier
Advances made in methods of synthesis of siloles during the period 1996 to the end of 2009
are described. The earliest general method involved reductive dimerization of tolan with …

Hydrosilylation of diynes as a route to functional polymers delocalized through silicon

JC Sanchez, WC Trogler - Macromolecular chemistry and …, 2008 - Wiley Online Library
Polycarbosilanes exhibit desirable physiochemical properties such as high thermal stability,
elastomeric behavior, diverse functional group tolerance, electronic delocalization, and ease …

Photoluminescent polymetalloles as chemical sensors

MJ Sailor, WC Trogler, H Sohn, RM Calhoun - US Patent 7,482,168, 2009 - Google Patents
(57) ABSTRACT A method to develop inexpensive inorganic polymeric sen sors that can
provide a sensitivity and selectivity for explosive nitroaromatic compounds. Selectivity is …

Syntheses of oligometalloles by catalytic dehydrocoupling

SJ Toal, H Sohn, LN Zakarov, WS Kassel… - …, 2005 - ACS Publications
The dehydrocoupling polycondensation of dihydro (tetraphenyl) metalloles (M= Si or Ge)
with 0.2 mol% H2PtCl6⊙ x H2O and excess cyclohexene produces the respective …