Mechanochemistry of pterodactylane
Pterodactylane is a [4]-ladderane with substituents on the central rung. Comparing the
mechanochemistry of the [4]-ladderane structure when pulled from the central rung versus …
mechanochemistry of the [4]-ladderane structure when pulled from the central rung versus …
Caged aiegens: Multicolor and white emission triggered by mechanical activation
Aggregation-induced emission luminogens (AIEgens) that respond to mechanical force are
increasingly used as force probes, memory devices, and advanced security systems. Most of …
increasingly used as force probes, memory devices, and advanced security systems. Most of …
Force Transduction Through Distant Force‐Bearing Regioisomeric Linkages Affects the Mechanochemical Reactivity of Cyclobutane
Fundamental understanding of mechanochemical reactivity is important for designing new
mechanophores. Besides the core structure of mechanophores, substituents on a …
mechanophores. Besides the core structure of mechanophores, substituents on a …
The Restoring Force Triangle: A Mnemonic Device for Polymer Mechanochemistry
In polymer mechanochemistry, mechanophores are specific molecular units within the
macromolecular backbone that are particularly sensitive to tension. To facilitate …
macromolecular backbone that are particularly sensitive to tension. To facilitate …
Solvent Polarity Effects on the Mechanochemistry of Spiropyran Ring Opening
Y Lin, TB Kouznetsova, AG Foret… - Journal of the American …, 2024 - ACS Publications
The spiropyran mechanophore (SP) is employed as a reporter of molecular tension in a
wide range of polymer matrices, but the influence of surrounding environment on the force …
wide range of polymer matrices, but the influence of surrounding environment on the force …
In-situ monitoring of polymer mechanochemistry: what can be learned from small molecule systems
N Willis-Fox - Frontiers in Chemistry, 2024 - frontiersin.org
Using mechanical energy to drive chemical transformations is an exciting prospect to
improve the sustainability of chemical reactions and to produce products not achievable by …
improve the sustainability of chemical reactions and to produce products not achievable by …
Mechanochemistry of cyclobutanes
R Obregon, J Wang - Science China Chemistry, 2024 - Springer
The field of polymer mechanochemistry has been revolutionized by implementing force-
responsive functional groups—mechanophores. The rational design of mechanophores …
responsive functional groups—mechanophores. The rational design of mechanophores …
Advancing the Mechanosensitivity of Atropisomeric Diarylethene Mechanophores through a Lever-Arm Effect
C Zhang, TB Kouznetsova, B Zhu… - Journal of the …, 2024 - ACS Publications
Understanding structure–mechanical activity relationships (SMARs) in polymer
mechanochemistry is essential for the rational design of mechanophores with desired …
mechanochemistry is essential for the rational design of mechanophores with desired …
A Thermally Stable SO2-Releasing Mechanophore: Facile Activation, Single-Event Spectroscopy, and Molecular Dynamic Simulations
Polymers that release small molecules in response to mechanical force are promising
candidates as next-generation on-demand delivery systems. Despite advancements in the …
candidates as next-generation on-demand delivery systems. Despite advancements in the …
Force-Activated Spin-Crossover in Fe2+ and Co2+ Transition Metal Mechanophores
Transition metal mechanophores exhibiting force-activated spin-crossover are attractive
design targets, yet large-scale discovery of them has not been pursued due in large part to …
design targets, yet large-scale discovery of them has not been pursued due in large part to …