Ammonia borane, a material with exceptional properties for chemical hydrogen storage

UB Demirci - International Journal of hydrogen energy, 2017 - Elsevier
Abstract Ammonia borane H 3 Nsingle bondBH 3, first reported in 1955, is isoelectronic with
ethane H 3 Csingle bondCH 3, but it has much different properties owing to (i) the nitrogen …

Ammonia-borane and related compounds as dihydrogen sources

A Staubitz, APM Robertson, I Manners - Chemical reviews, 2010 - ACS Publications
We recently reviewed the latest developments in the chemistry of amine-and phosphine-
borane adducts R3E· BR′ 3 (R, R′) alkyl, aryl, halogen, or H etc., E) N or P) where we …

A review of high density solid hydrogen storage materials by pyrolysis for promising mobile applications

Y Huang, Y Cheng, J Zhang - Industrial & Engineering Chemistry …, 2021 - ACS Publications
Hydrogen is one of the cleanest energies with potential to have zero carbon emission.
Hydrogen storage is a challenging phase for the hydrogen energy application. The safety …

Pyrolytic decomposition of ammonia borane to boron nitride

S Frueh, R Kellett, C Mallery, T Molter… - Inorganic …, 2011 - ACS Publications
The thermal decomposition of ammonia borane was studied using a variety of methods to
qualitatively identify gas and remnant solid phase species after thermal treatments up to …

A Non‐π‐Conjugated Molecular Crystal with Balanced Second‐Harmonic Generation, Bandgap, and Birefringence

Y Zhou, N He, Z Lin, X Shang, X Chen, Y Li, W Huang… - Small, 2024 - Wiley Online Library
Traditional nonlinear optical (NLO) crystals are exclusively limited to ionic crystals with π‐
conjugated groups and it is a great challenge to achieve a subtle balance between second …

Development of amidoboranes for hydrogen storage

YS Chua, P Chen, G Wu, Z Xiong - Chemical Communications, 2011 - pubs.rsc.org
With high hydrogen content and moderate dehydrogenation conditions, metal
amidoboranes have been regarded as potential hydrogen storage candidates and have …

New perspectives on potential hydrogen storage materials using high pressure

Y Song - Physical Chemistry Chemical Physics, 2013 - pubs.rsc.org
In addressing the global demand for clean and renewable energy, hydrogen stands out as
the most suitable candidate for many fuel applications that require practical and efficient …

Synthesis of ammonia borane for hydrogen storage applications

DJ Heldebrant, A Karkamkar, JC Linehan… - Energy & Environmental …, 2008 - pubs.rsc.org
A new synthetic procedure to make the condensed phase hydrogen storage material,
ammonia borane (NH3BH3, abbreviated as AB), is described and compared with previous …

Ammonia borane, past as prolog

H Li, Q Yang, X Chen, SG Shore - Journal of Organometallic Chemistry, 2014 - Elsevier
Abstract Ammonia borane (NH 3 BH 3), the simplest of the amine boranes, has yielded its
secrets grudgingly since its first attempted synthesis in 1923. Here we review aspects of its …

Access to adducts of parent iminoborane isomers, HBNH and NBH 2, using frustrated Lewis pair chelation

BL Frenette, AA Omaña, MJ Ferguson… - Chemical …, 2021 - pubs.rsc.org
Adducts of the parent iminoborane isomers, HBNH and NBH2, have been prepared, each
stabilized by the frustrated Lewis pair (FLP) chelate iPr2P (C6H4) BCy2 (PB). PB {HBNH} …