Recent development of aryl diazonium chemistry for the derivatization of aromatic compounds

F Mo, D Qiu, L Zhang, J Wang - Chemical Reviews, 2021 - ACS Publications
Aryl diazonium salts are versatile building blocks in organic synthesis. In light of the ever-
increasing importance of aryl diazonium salts spanning most disciplines of the chemical …

Biosynthesis of CuO nanoparticles using aqueous extract of herbal tea (Stachys Lavandulifolia) flowers and evaluation of its catalytic activity

H Veisi, B Karmakar, T Tamoradi, S Hemmati… - Scientific Reports, 2021 - nature.com
Plant derived biogenic synthesis of nanoparticles (NP) has been the recent trend in material
science as featured sustainable catalysts. A great deal of the current nanocatalytic research …

Aromatic substitutions of arenediazonium salts via metal catalysis, single electron transfer, and weak base mediation

D Koziakov, G Wu, AJ von Wangelin - Organic & Biomolecular …, 2018 - pubs.rsc.org
The re-discovery of arenediazonium salts as stable and easily accessible electrophiles for
radical aromatic substitutions initiated by single-electron transfer has led to the development …

Efficient ruthenium-catalyzed N-methylation of amines using methanol

TT Dang, B Ramalingam, AM Seayad - ACS Catalysis, 2015 - ACS Publications
An in situ-generated complex from [RuCp* Cl2] 2 and dpePhos ligand is reported as an
efficient catalyst in the presence of 5 mol% of LiOtBu for the N-methylation of amines using …

Is Cu (III) a necessary intermediate in Cu-mediated coupling reactions? A mechanistic point of view

SJ Li, Y Lan - Chemical Communications, 2020 - pubs.rsc.org
The mechanism of copper-mediated coupling reactions has aroused widespread interest,
and it has been found to not be as simple as initially thought. In this article, we give an …

Copper-catalyzed O-arylation of phenols with diazonium salts

X Fang, C Qi, X Cao, ZG Ren, DJ Young, HX Li - Green Chemistry, 2023 - pubs.rsc.org
It is well known that diazonium salts (ArN2+) react with phenols (Ar′ OH) to give aryl
diazoethers or diazo compounds, but their cross-coupling to exclusively access diaryl ethers …

Biogenic nano-CuO-catalyzed facile C–N cross-coupling reactions: scope and mechanism

M Halder, MM Islam, Z Ansari… - ACS Sustainable …, 2017 - ACS Publications
We demonstrate here a green and efficient biogenic synthesis of copper (II) oxide
nanoparticles using easily available Ocimum Sanctum leaf extract at room temperature. The …

One-Pot Synthesis of 1-Aryl-3-trifluoromethylpyrazoles Using Nitrile Imines and Mercaptoacetaldehyde As a Surrogate of Acetylene

K Świątek, G Utecht-Jarzyńska, M Palusiak… - Organic …, 2023 - ACS Publications
A synthetically useful approach for one-pot preparation of 1-aryl-3-trifluoromethylpyrazoles
using in situ generated nitrile imines and mercaptoacetaldehyde applied as 1 equiv of …

Copper nanoparticle anchored biguanidine-modified Zr-UiO-66 MOFs: a competent heterogeneous and reusable nanocatalyst in Buchwald–Hartwig and Ullmann …

H Veisi, N Neyestani, M Pirhayati, SA Kamangar… - RSC …, 2021 - pubs.rsc.org
We have designed a functionalized metal–organic framework (MOF) of UiO topology as a
support, with an extremely high surface area, adjustable pore sizes and stable crystalline …

Efficient N-arylation of azole compounds utilizing selective aryl-transfer TMP-iodonium (III) reagents

D Koseki, E Aoto, T Shoji, K Watanabe, Y In, Y Kita… - Tetrahedron …, 2019 - Elsevier
It was determined that diaryliodonium (III) triflates bearing a trimethoxybenzene (TMP)
auxiliary are more reactive than the reported selective aryl-transfer iodonium salts in the N …