Metastability at defective metal oxide interfaces and nanoconfined structures
V Esposito, IE Castelli - Advanced Materials Interfaces, 2020 - Wiley Online Library
Most of the paradigms in materials science and technology firmly rely on equilibrium
materials, ie, phases with the lowest Gibbs energy under thermodynamic conditions. In …
materials, ie, phases with the lowest Gibbs energy under thermodynamic conditions. In …
Boosting the performance and durability of Ni/YSZ cathode for hydrogen production at high current densities via decoration with nano-sized electrocatalysts
S Ovtar, X Tong, JJ Bentzen, KTS Thydén… - Nanoscale, 2019 - pubs.rsc.org
Conventional Ni/yttria-stabilized zirconia (YSZ) electrodes in solid oxide cells experience
fast degradation when operated for the electrolysis of steam at high current densities. This …
fast degradation when operated for the electrolysis of steam at high current densities. This …
Cold sintering-assisted densification of GDC electrolytes for SOFC applications
M Murutoglu, T Ucun, O Ulasan, A Buyukaksoy… - International Journal of …, 2022 - Elsevier
Cold sintering is a novel technique that promotes the densification of ceramics at a much
reduced temperature as compared to conventionally sintered ones. With the aid of this …
reduced temperature as compared to conventionally sintered ones. With the aid of this …
Effect of oxygen defects blocking barriers on gadolinium doped ceria (GDC) electro-chemo-mechanical properties
Some oxygen defective metal oxides, such as cerium and bismuth oxides, have recently
shown exceptional electrostrictive properties that are even superior to the best performing …
shown exceptional electrostrictive properties that are even superior to the best performing …
[HTML][HTML] Electromechanical coupling in alkaline-earth doped-ceria ceramics
Oxygen-deficient cerium oxide ceramics exhibit an anomalously high electromechanical
response called giant electrostriction. This feature has been linked to the polarization and …
response called giant electrostriction. This feature has been linked to the polarization and …
[HTML][HTML] When two become one: An insight into 2D conductive oxide interfaces
N Pryds, V Esposito - Journal of Electroceramics, 2017 - Springer
Recent progress has led to conductance confinement at the interface of complex oxide
heterostructures, thereby providing new opportunities to explore nano-electronic as well as …
heterostructures, thereby providing new opportunities to explore nano-electronic as well as …
Accelerated ceria–zirconia solubilization by cationic diffusion inversion at low oxygen activity
V Esposito, D Marani, F Teocoli, KTS Thydén… - Journal of Materials …, 2016 - pubs.rsc.org
Fast elemental diffusion at the Gd-doped ceria/Y-stabilized zirconia interface occurs under
reducing conditions at low oxygen activity (pO2< 10− 12 atm) and high temperature (1400° …
reducing conditions at low oxygen activity (pO2< 10− 12 atm) and high temperature (1400° …
Field-assisted sintering/spark plasma sintering of gadolinium-doped ceria with controlled re-oxidation for crack prevention
Gadolinium-Doped Ceria (GDC) is a prospective material for application in electrochemical
devices. Free sintering in air of GDC powder usually requires temperatures in the range of …
devices. Free sintering in air of GDC powder usually requires temperatures in the range of …
Effect of cold sintering process (CSP) on the electro-chemo-mechanical properties of Gd-doped ceria (GDC)
In this report, the effect of the cold sintering process (CSP) on the electro-chemo-mechanical
properties of 10 mol% Gd-doped ceria (GDC) is investigated. High purity nanoscale GDC …
properties of 10 mol% Gd-doped ceria (GDC) is investigated. High purity nanoscale GDC …
Enhanced electromechanical response in Sm and Nd Co-doped Ceria
Highly oxygen defective cerium oxide, eg, Gd-doped ceria, is a sustainable non-classical
electrostrictor with electromechanical properties that are superior to lead-based …
electrostrictor with electromechanical properties that are superior to lead-based …