Self-assembly of octanuclear Ln (III)-based clusters: their large magnetocaloric effects and highly efficient conversion of CO 2

WM Wang, XY Xin, N Qiao, ZL Wu, L Li, JY Zou - Dalton Transactions, 2022 - pubs.rsc.org
The design and construction of high-nuclear lanthanide clusters with fascinating topology
and functional properties have been an active area of research, however, the development …

Molecular assemblies from linear-shaped Ln 4 clusters to Ln 8 clusters using different β-diketonates: disparate magnetocaloric effects and single-molecule magnet …

WM Wang, ZL Wu, JZ Cui - Dalton Transactions, 2021 - pubs.rsc.org
A series of tetranuclear lanthanide-based clusters [Ln4 (dbm) 6 (L) 2 (CH3OH) 4]· 2CH3OH
(Ln (III)= Gd (1), Dy (2), and Ho (3); H3L= 2-[(2-(hydroxyimino) propanehydrazide) methyl]-2 …

Densely packed lanthanide cubane based 3D metal–organic frameworks for efficient magnetic refrigeration and slow magnetic relaxation

S Biswas, AK Mondal, S Konar - Inorganic Chemistry, 2016 - ACS Publications
Two isostructural densely packed squarato-bridged lanthanide-based 3D metal–organic
frameworks (MOFs)[Ln5 (μ3-OH) 5 (μ3-O)(CO3) 2 (HCO2) 2 (C4O4)(H2O) 2][Ln= Gd (1) and …

Wheel-like Ln18 Cluster Organic Frameworks for Magnetic Refrigeration and Conversion of CO2

TQ Song, J Dong, AF Yang, XJ Che, HL Gao… - Inorganic …, 2018 - ACS Publications
Two isostructural 2D MOFs ([Ln7 (CDA) 6 (HCOO) 3 (μ3-OH) 6 (H2O) 8] n, abbreviated as 1-
Gd and 2-Dy) were successfully synthesized under solvothermal conditions. The self …

Coordination‐Cluster‐Based Molecular Magnetic Refrigerants

S Zhang, P Cheng - The Chemical Record, 2016 - Wiley Online Library
Coordination polymers serving as molecular magnetic refrigerants have been attracting
great interest. In particular, coordination cluster compounds that demonstrate their apparent …

Pentanuclear Yb (III) cluster-based metal-organic frameworks as heterogeneous catalysts for CO2 conversion

N Wei, Y Zhang, L Liu, ZB Han, DQ Yuan - Applied Catalysis B …, 2017 - Elsevier
Two porous metal-organic frameworks (MOFs) incorporating pentanuclear Yb (III) clusters
and pyridyl-supported tetracarboxylates or pyridyl carboxylic acid-supported …

Principles for creating “molecular refrigerators” derived from Gadolinium (III) coordination compounds: a review

AV Pavlishchuk, VV Pavlishchuk - Theoretical and Experimental Chemistry, 2020 - Springer
Theoretical aspects of the magnetocaloric effect of coordination compounds, which hold
promise for the design of new cooling agents termed “molecular refrigerators,” is examined …

Channel-Assisted Proton Conduction Behavior in Hydroxyl-Rich Lanthanide-Based Magnetic Metal–Organic Frameworks

S Biswas, J Chakraborty, V Singh Parmar… - Inorganic …, 2017 - ACS Publications
Two new lanthanide-based 3D metal–organic frameworks (MOFs),{[Ln (L)(Ox)(H2O)] n· x
H2O}[Ln= Gd3+ and x= 3 (1) and Dy3+ and x= 1.5 (2); H2L= mucic acid; OxH2= oxalic acid] …

Large magnetocaloric effect and remarkable single-molecule-magnet behavior in triangle-assembled Ln III6 clusters

WM Wang, RX Yue, Y Gao, MJ Wang, SS Hao… - New Journal of …, 2019 - pubs.rsc.org
Two new and interesting polynuclear lanthanide clusters, namely,[Ln6 (acac) 4 (HL) 2
(THAM) 4 (CH3COCH3) 2]· 2CH3OH (LnIII= Gd (1) and Dy (2), Hacac= acetylacetone, H3L …

Enhancement of Magnetocaloric Effect through Fixation of Carbon Dioxide: Molecular Assembly from Ln4 to Ln4 Cluster Pairs

J Wu, XL Li, L Zhao, M Guo, J Tang - Inorganic Chemistry, 2017 - ACS Publications
A series 1. Ln of tetranuclear lanthanide clusters [Ln4 (μ4-O) L2 (PhCOO) 6]· solvent (Ln=
Gd (1. Gd), Dy (1. Dy), Ho (1. Ho)) and octanuclear lanthanide Ln4 cluster pairs 2. Ln [Ln8 …