Stability of Photocathodes: A Review on Principles, Design, and Strategies

Q Wang, J Liu, Q Li, J Yang - ChemSusChem, 2023 - Wiley Online Library
Photoelectrochemical devices based on semiconductor photoelectrode can directly convert
and store solar energy into chemical fuels. Although the efficient photoelectrodes with …

Understanding the stability of semiconducting photocathodes for solar water splitting

W Yu - Current Opinion in Electrochemistry, 2023 - Elsevier
Semiconductor photoelectrochemistry is a powerful means for efficient conversion of solar
energy to chemical fuels. Practical implementation of this promising technology has been …

Stable solar water splitting with wettable organic-layer-protected silicon photocathodes

B Wu, T Wang, B Liu, H Li, Y Wang, S Wang… - Nature …, 2022 - nature.com
Protective layers are essential for Si-based photocathodes to achieve long-term stability.
The conventionally used inorganic protective layers, such as TiO2, need to be free of …

Substantial lifetime enhancement for Si-based photoanodes enabled by amorphous TiO2 coating with improved stoichiometry

Y Dong, M Abbasi, J Meng, L German, C Carlos… - Nature …, 2023 - nature.com
Amorphous titanium dioxide (TiO2) film coating by atomic layer deposition (ALD) is a
promising strategy to extend the photoelectrode lifetime to meet the industrial standard for …

Strategies To Construct n-Type Si-Based Heterojunctions for Photoelectrochemical Water Oxidation

Y Li, Y Xiao, C Wu, D Zhang, J Huang… - ACS Materials …, 2022 - ACS Publications
Silicon (Si) is a suitable absorber for constructing highly efficient solar cells and
photoelectrodes, because of its narrow band gap (1.12 eV), Earth abundance, and excellent …

Nanopixelated cuprous oxide photocathodes for durable photoelectrochemical water splitting

J Lee, J Oh - ACS Energy Letters, 2022 - ACS Publications
Cuprous oxide (Cu2O) has attracted extensive attention for use in the production of
hydrogen through photoelectrochemical water-splitting reactions. However, because the …

Condensed Layer Deposition of Nanoscopic TiO2 Overlayers on High-Surface-Area Electrocatalysts

DV Fraga Alvarez, Z Lin, Z Shi, AF Baxter… - … Applied Materials & …, 2024 - ACS Publications
Encapsulating an electrocatalytic material with a semipermeable, nanoscopic oxide
overlayer offers a promising approach to enhancing its stability, activity, and/or selectivity …

Scaling-up of thin-film photoelectrodes for solar Water splitting based on atomic layer deposition

X Wang, G Zhang, B Liu, Y Wang, C Zhao… - … Applied Materials & …, 2022 - ACS Publications
Atomic layer deposition (ALD) is an established method to prepare protective layers for Si-
based photoelectrodes for photoelectrochemical (PEC) water splitting. Although ALD has …

Investigations of the stability of GaAs for photoelectrochemical H 2 evolution in acidic or alkaline aqueous electrolytes

W Yu, MH Richter, E Simonoff… - Journal of Materials …, 2021 - pubs.rsc.org
The long-term stability of p-GaAs photocathodes has been investigated for the hydrogen-
evolution reaction (HER) in contact with either 1.0 M H2SO4 (aq) or 1.0 M KOH (aq). Stability …

Catalytic open-circuit passivation by thin metal oxide films of p-Si anodes in aqueous alkaline electrolytes

HJ Fu, P Buabthong, ZP Ifkovits, W Yu… - Energy & …, 2022 - pubs.rsc.org
Ni and NiOx-based protective thin films are shown to catalyze the oxidation of Si in the
presence of O2 in strongly alkaline KOH (aq) even in the absence of illumination. The O2 in …