Recent advances in stable main group element radicals: preparation and characterization
Radical species are significant in modern chemistry. Their unique chemical bonding and
novel physicochemical properties play significant roles not only in fundamental chemistry …
novel physicochemical properties play significant roles not only in fundamental chemistry …
Efficient Narrowband Circularly Polarized Light Emitters Based on 1, 4‐B, N‐embedded Rigid Donor–Acceptor Helicenes
Narrow‐band emission is essential for applicable circularly polarized luminescence (CPL)
active materials in ultrahigh‐definition CP‐OLEDs. One of the most promising classes of …
active materials in ultrahigh‐definition CP‐OLEDs. One of the most promising classes of …
NHC induced radical formation via homolytic cleavage of B–B bonds and its role in organic reactions
L Kuehn, L Zapf, L Werner, M Stang… - Chemical …, 2022 - pubs.rsc.org
New borylation methodologies have been reported recently, wherein diboron (4)
compounds apparently participate in free radical couplings via the homolytic cleavage of the …
compounds apparently participate in free radical couplings via the homolytic cleavage of the …
Helically Chiral Donor–Acceptor Double Hetero [4] helicenes with Circularly Polarized Thermally Activated Delayed Fluorescence
C Qu, Y Zhu, L Liang, K Ye, Y Zhang… - Advanced Optical …, 2023 - Wiley Online Library
Although helically chiral heterohelicenes are widely adopted in chiroptical studies, those
with circularly polarized thermally activated delayed fluorescence (CP‐TADF), which are …
with circularly polarized thermally activated delayed fluorescence (CP‐TADF), which are …
Bridging of Cove Regions: A Strategy for Realizing Persistently Chiral Double Heterohelicenes with Attractive Luminescent Properties
C Qu, Y Xu, Y Wang, Y Nie, K Ye… - Angewandte Chemie …, 2024 - Wiley Online Library
The racemization of chiral organic compounds is a common chemical phenomenon.
However, it often poses configurational‐stability issues to the application of this class of …
However, it often poses configurational‐stability issues to the application of this class of …
D− π− A Type [7] Helicene‐like Imide Derivatives with Tunable Photophysical Properties and Circularly Polarized Luminescence
L Li, K Xu, T Qi - Chemistry–A European Journal, 2024 - Wiley Online Library
Helicenes and their derivatives show great application prospects as circularly polarized
luminescence (CPL) materials, but their fluorescence quantum yields (ΦFLs) need a …
luminescence (CPL) materials, but their fluorescence quantum yields (ΦFLs) need a …
Enhanced optical properties of azaborole helicenes by lateral and helical extension
F Full, Q Wölflick, K Radacki… - … A European Journal, 2022 - Wiley Online Library
The synthesis and characterization of laterally extended azabora [5]‐,‐[6]‐and‐[7] helicenes,
assembled from N‐heteroaromatic and dibenzo [g, p] chrysene building blocks is described …
assembled from N‐heteroaromatic and dibenzo [g, p] chrysene building blocks is described …
Narrowband Blue Circularly Polarized Luminescence Emitter Based on BN‐Doped Benzo [6] helicene with Stimuli‐Responsive Properties
M Liu, C Li, G Liao, F Zhao, C Yao… - … –A European Journal, 2024 - Wiley Online Library
Boron‐doped helicenes, known for their unique electronic and photophysical properties, are
of great interest for numerous applications. This research introduces two new azabora [6] …
of great interest for numerous applications. This research introduces two new azabora [6] …
Synthesis and isolation of dinuclear N, C-chelate organoboron compounds bridged by neutral, anionic, and dianionic 4, 4′-bipyridine via reductive coupling of …
HJ Li, R Feng, X Shi, J Wei, Z Xi - Dalton Transactions, 2022 - pubs.rsc.org
The reaction of Bppy (Mes) 2 (BN1; ppy= 2-phenylpyridine) and BCH2ppy (Mes) 2 (BN3)
with the reducing reagent KC8 resulted in C–C bond formation via intermolecular radical …
with the reducing reagent KC8 resulted in C–C bond formation via intermolecular radical …
A Selenenium-Bridged 10-Boratriptycene Lewis Acid
A non-planar triarylborane and a new member of the boratriptycene family bearing a
selenium atom in bridgehead position of triptycene scaffold was generated and isolated as a …
selenium atom in bridgehead position of triptycene scaffold was generated and isolated as a …