Strains and stresses in coordination compounds

P Comba - Coordination chemistry reviews, 1999 - Elsevier
The possible ways to induce strain in coordination compounds and the quantification of
steric effects and their influence on molecular properties are discussed. Based on various …

The spin-states and spin-transitions of mononuclear iron (II) complexes of nitrogen-donor ligands

MA Halcrow - Polyhedron, 2007 - Elsevier
A survey of mononuclear iron (II) complexes with heterocyclic N-donor ligation is presented.
A brief introduction to spin-crossover chemistry and low-temperature spin-trapping is …

Exceptional manganese (II) stability and manganese (II)/zinc (II) selectivity with rigid polydentate ligands

P Cieslik, P Comba, B Dittmar, D Ndiaye… - Angewandte …, 2022 - Wiley Online Library
While MnII complexes meet increasing interest in biomedical applications, ligands are
lacking that enable high MnII complex stability and selectivity vs. ZnII, the most relevant …

Highly Stabilized Low-Spin Iron(III) and Cobalt(III) Complexes of a Tridentate Bis-Amide Ligand 2,6-Bis(N-phenylcarbamoyl)pyridine. Novel Nonmacrocyclic …

M Ray, D Ghosh, Z Shirin, R Mukherjee - Inorganic chemistry, 1997 - ACS Publications
Two novel low-spin complexes,[Et4N][FeL2]⊙ 1.5 H2O (1) and [Et4N][CoL2]⊙ 2H2O (2)(L is
a deprotonated bis-amide ligand), have been synthesized and characterized. Four relatively …

Dipicolylamine Complexes of Copper(II):  Two Different Coordination Geometries in the Same Unit Cell of Cu(Dipica)2(BF4)2

M Palaniandavar, RJ Butcher, AW Addison - Inorganic chemistry, 1996 - ACS Publications
Bright blue Cu (Dipica) 2 (BF4) 2 crystallizes in the monoclinic space group P 21/n, with unit
cell parameters a= 23.406 (6) Å, b= 9.338 (2) Å, c= 25.573 (7) Å, β= 95.39 (2)°, and Z= 8 …

Tetrapodal pentadentate nitrogen ligands: Aspects of complex structure and reactivity

A Grohmann - Advances in Inorganic Chemistry, 2004 - Elsevier
Publisher Summary This chapter describes tetrapodal pentadentate nitrogen ligands.
Tetrapodal pentadentate ligands have the ability to stabilize transition metal centers …

Carboxamido nitrogens are good donors for Fe (III): syntheses, structures, and properties of two low-spin nonmacrocyclic iron (III) complexes with tetracarboxamido-N …

DS Marlin, MM Olmstead, PK Mascharak - Inorganic chemistry, 1999 - ACS Publications
Two nonmacrocyclic ligands with pyridine and carboxamide nitrogens as donors readily
form bis complexes of the type [FeIIIL2]+ in which the Fe (III) centers exhibit preference for …

Iron Carbonyl, Nitrosyl, and Nitro Complexes of a Tetrapodal Pentadentate Amine Ligand: Synthesis, Electronic Structure, and Nitrite Reductase‐like Reactivity

J Pitarch López, FW Heinemann… - … A European Journal, 2002 - Wiley Online Library
The tetrapodal pentaamine 2, 6-C5H3N [CMe (CH2NH2) 2] 2 (pyN4, 1) forms a series of
octahedral iron (ii) complexes of general formula [Fe (L)(1)] Xn with a variety of …

[PDF][PDF] Cobalt

PV Bernhardt, G Lawrance - 2004 - core.ac.uk
CObalt Page 1 (S. 1 CObalt PV BERNHARDT University of Oueensland, Brisbane, Australia
and (GA LAWRANCE University of Newcastle, Callaghan, Australia = kk * kk 6 …

Synthesis and characterization of bis (di-2-pyridylmethanamine) ruthenium (II)

J Chang, S Plummer, ESF Berman, D Striplin… - Inorganic …, 2004 - ACS Publications
The complex Ru (dipa) 22+(dipa= di-2-pyridylmethanamine) has been prepared, yielding
approximately a statistical ratio of the meso and rac isomers. The electronic spectra of both …