Heteroatom-based diradical (oid) s

A Hinz, J Bresien, F Breher, A Schulz - Chemical Reviews, 2023 - ACS Publications
Heteroatom-centered diradical (oid) s have been in the focus of molecular main group
chemistry for nearly 30 years. During this time, the diradical concept has evolved and the …

Multiphase chemistry at the atmosphere–biosphere interface influencing climate and public health in the anthropocene

U Pöschl, M Shiraiwa - Chemical reviews, 2015 - ACS Publications
Multiphase chemistry plays a vital role in the Earth system, climate, and health. Chemical
reactions, mass transport, and phase transitions between gases, liquids, and solids are …

Direct observation of bimolecular reactions of ultracold KRb molecules

MG Hu, Y Liu, DD Grimes, YW Lin, AH Gheorghe… - Science, 2019 - science.org
Femtochemistry techniques have been instrumental in accessing the short time scales
necessary to probe transient intermediates in chemical reactions. In this study, we took the …

Photo-excitation of long-lived transient intermediates in ultracold reactions

Y Liu, MG Hu, MA Nichols, DD Grimes, T Karman… - Nature Physics, 2020 - nature.com
In many chemical reactions, the transformation from reactants to products is mediated by
transient intermediate complexes. For gas-phase reactions involving molecules with a few …

Atmospheric chemistry of Criegee intermediates: Unimolecular reactions and reactions with water

B Long, JL Bao, DG Truhlar - Journal of the American Chemical …, 2016 - ACS Publications
Criegee intermediates are produced in the ozonolysis of unsaturated hydrocarbons in the
troposphere, and understanding their fate is a prerequisite to modeling climate-controlling …

Criegee intermediates and their impacts on the troposphere

MAH Khan, CJ Percival, RL Caravan… - … Science: Processes & …, 2018 - pubs.rsc.org
Criegee intermediates (CIs), carbonyl oxides formed in ozonolysis of alkenes, play key roles
in the troposphere. The decomposition of CIs can be a significant source of OH to the …

The molecular identification of organic compounds in the atmosphere: state of the art and challenges

B Noziere, M Kalberer, M Claeys, J Allan… - Chemical …, 2015 - ACS Publications
The Earth's atmosphere offers a striking contrast with other known planets by its rich organic
composition, which results almost exclusively from the presence of life on the planet. About …

Direct kinetic measurement of the reaction of the simplest Criegee intermediate with water vapor

W Chao, JT Hsieh, CH Chang, JJM Lin - Science, 2015 - science.org
Carbonyl oxides, or Criegee intermediates, are important transient species formed in the
reactions of unsaturated hydrocarbons with ozone. Although direct detection of Criegee …

Chemistry of atmospheric nucleation: on the recent advances on precursor characterization and atmospheric cluster composition in connection with atmospheric new …

M Kulmala, T Petäjä, M Ehn, J Thornton… - Annual review of …, 2014 - annualreviews.org
The recent development in measurement techniques and theoretical understanding has
enabled us to study atmospheric vapor, cluster and nanoparticle concentrations, dynamics …

Bimolecular chemistry in the ultracold regime

Y Liu, KK Ni - Annual review of physical chemistry, 2022 - annualreviews.org
Advances in atomic, molecular, and optical physics techniques allowed the cooling of simple
molecules down to the ultracold regime (1 mK) and opened opportunities to study chemical …