Light-Emitting Self-Assembled Materials Based on d8 and d10 Transition Metal Complexes

VWW Yam, VKM Au, SYL Leung - Chemical reviews, 2015 - ACS Publications
The spontaneous self-organization of matters has always been one of the most fascinating
wonders in the world. Self-assembly refers to “the autonomous organization of components …

Stimuli-responsive metal–ligand assemblies

AJ McConnell, CS Wood, PP Neelakandan… - Chemical …, 2015 - ACS Publications
Within living systems, molecular-scale responses to stimuli flow together into the intricate
and robust signal transduction networks that process information for an organism. Studies of …

Mechanoresponsive luminescent molecular assemblies: an emerging class of materials

Y Sagara, S Yamane, M Mitani, C Weder… - Advanced …, 2016 - Wiley Online Library
The possibility to change the molecular assembled structures of organic and organometallic
materials through mechanical stimulation is emerging as a general and powerful concept for …

Innovative molecular design strategies in materials science following the aurophilicity concept

N Mirzadeh, SH Privér, AJ Blake, H Schmidbaur… - Chemical …, 2020 - ACS Publications
The past decade has seen a diverse range of breakthrough inventions that are derived from
gold complexes, including the application of aurophilic interactions in the preparation of …

Aurophilic interactions in the self‐assembly of gold nanoclusters into nanoribbons with enhanced luminescence

Z Wu, Y Du, J Liu, Q Yao, T Chen, Y Cao… - Angewandte Chemie …, 2019 - Wiley Online Library
Abstract Aurophilic interactions (AuI⋅⋅⋅ AuI) are crucial in directing the supramolecular self‐
assembly of many gold (I) compounds; however, this intriguing chemistry has been rarely …

Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry

H Clavier, SP Nolan - Chemical Communications, 2010 - pubs.rsc.org
Electronic and steric ligand effects both play major roles in organometallic chemistry and
consequently in metal-mediated catalysis. Quantifying such parameters is of interest to …

[HTML][HTML] Nanohybrids of atomically precise metal nanoclusters

K Sahoo, TR Gazi, S Roy, I Chakraborty - Communications Chemistry, 2023 - nature.com
Atomically precise metal nanoclusters (NCs) with molecule-like structures are emerging
nanomaterials with fascinating chemical and physical properties. Photoluminescence (PL) …

Polymorphism and reversible mechanochromic luminescence for solid-state difluoroboron avobenzone

G Zhang, J Lu, M Sabat, CL Fraser - Journal of the American …, 2010 - ACS Publications
Difluoroboron avobenzone (BF2AVB), a simple boron complex of a commercial sunscreen
product, exhibits morphology-dependent emission and mechanochromic luminescence in …

A briefing on aurophilicity

H Schmidbaur, A Schier - Chemical Society Reviews, 2008 - pubs.rsc.org
There is now compelling experimental evidence for the existence of specific intra-and
intermolecular bonding between seemingly closed-shell gold (I) centers (5d10) which …

Polymorphic copper iodide clusters: insights into the mechanochromic luminescence properties

Q Benito, XF Le Goff, S Maron, A Fargues… - Journal of the …, 2014 - ACS Publications
An in-depth study of mechanochromic and thermochromic luminescent copper iodide
clusters exhibiting structural polymorphism is reported and gives new insights into the origin …