Iron photoredox catalysis–past, present, and future
Photoredox catalysis of organic reactions driven by iron has attracted substantial attention
throughout recent years, due to potential environmental and economic benefits. In this …
throughout recent years, due to potential environmental and economic benefits. In this …
Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII
Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …
valence electron configurations have outstanding photophysical and photochemical …
The great strides of iron photosensitizers for contemporary organic photoredox catalysis: On our way to the holy grail?
The scarcity of 2 nd and 3 rd row transition metals such as ruthenium, iridium, rhodium and
osmium, coupled with a global desire for sustainable chemistry has led to the resurgence of …
osmium, coupled with a global desire for sustainable chemistry has led to the resurgence of …
Ferrous and ferric complexes with cyclometalating N-heterocyclic carbene ligands: a case of dual emission revisited
Iron N-heterocyclic carbene (FeNHC) complexes with long-lived charge transfer states are
emerging as a promising class of photoactive materials. We have synthesized [FeII (ImP) …
emerging as a promising class of photoactive materials. We have synthesized [FeII (ImP) …
Photosensitized activation of diazonium derivatives for C–B bond formation
A Ripak, S De Kreijger, RN Sampaio, CA Vincent… - Chem catalysis, 2023 - cell.com
Aryl diazonium salts are ubiquitous building blocks in chemistry, as they are useful radical
precursors in organic synthesis as well as for the functionalization of solid materials. They …
precursors in organic synthesis as well as for the functionalization of solid materials. They …
Luminescence and Excited-State Reactivity in a Heteroleptic Tricyanido Fe (III) Complex
Y Ye, P Garrido-Barros, J Wellauer… - Journal of the …, 2023 - ACS Publications
Harnessing sunlight via photosensitizing molecules is key for novel optical applications and
solar-to-chemical energy conversion. Exploiting abundant metals such as iron is attractive …
solar-to-chemical energy conversion. Exploiting abundant metals such as iron is attractive …
A new era of LMCT: leveraging ligand-to-metal charge transfer excited states for photochemical reactions
AM May, JL Dempsey - Chemical Science, 2024 - pubs.rsc.org
Ligand-to-metal charge transfer (LMCT) excited states are capable of undergoing a wide
array of photochemical reactions, yet receive minimal attention compared to other charge …
array of photochemical reactions, yet receive minimal attention compared to other charge …
Factors that Impact Photochemical Cage Escape Yields
The utilization of visible light to mediate chemical reactions in fluid solutions has
applications that range from solar fuel production to medicine and organic synthesis. These …
applications that range from solar fuel production to medicine and organic synthesis. These …
Spectroscopic Techniques to Unravel Mechanistic Details in Light‐Induced Transformations and Photoredox Catalysis
The rapid development of photo (redox) catalysis within the last decades is remarkable to
the extent that the utilization of light‐driven processes in organic chemistry has become a …
the extent that the utilization of light‐driven processes in organic chemistry has become a …
Investigation of the Excited-State Electron Transfer and Cage Escape Yields Between Halides and a Fe (III) Photosensitizer
S De Kreijger, A Ripak, B Elias… - Journal of the American …, 2024 - ACS Publications
Excited-state quenching and reduction of [Fe (phtmeimb) 2]+, where phtmeimb is phenyl [tris
(3-methyl-imidazolin-2-ylidene)] borate, with iodide, bromide, and chloride were studied in …
(3-methyl-imidazolin-2-ylidene)] borate, with iodide, bromide, and chloride were studied in …