Recent advances in the synthesis of benzo [b] furans

MM Heravi, V Zadsirjan - Advances in Heterocyclic Chemistry, 2015 - Elsevier
Benzofuran itself is an oily chemical compound, extracted from coal tar, which is converted
into a synthetic resin, used in different industries. Several derivatives of benzofuran occur …

Sustainable hydration of alkynes promoted by first row transition metal complexes. Background, highlights and perspectives

R Salvio, M Bassetti - Inorganica Chimica Acta, 2021 - Elsevier
The review describes the state of the art in hydration reactions of alkynes by direct or indirect
catalysis of first row transition metal complexes, covering mostly the literature of the last …

Diastereoselective decarboxylative alkynylation of anomeric carboxylic acids using Cu/photoredox dual catalysis

M Zhu, S Messaoudi - ACS Catalysis, 2021 - ACS Publications
Alkynyl C-nucleosides are of high value for various applications; however, their synthesis
remains underexplored. Here we report a simple route toward the synthesis of alkynyl C …

Hydration of unsymmetrical internal alkynes: factors governing the regioselectivity

X Liu, JL Pozzo, A Hamze, M Alami, O Provot - ACS Catalysis, 2023 - ACS Publications
Water addition on an unsymmetrical internal alkyne has significance in organic chemistry
and has stimulated challenging approaches to access a highly regioselective process …

Palladium-Catalyzed C–S Coupling: Access to Thioethers, Benzo[b]thiophenes, and Thieno[3,2-b]thiophenes

M Kuhn, FC Falk, J Paradies - Organic Letters, 2011 - ACS Publications
The first C–S bond formation/cross-coupling/cyclization domino reaction using thiourea as a
cheap and easy to handle dihydrosulfide surrogate has been developed. Structurally …

Regioselective metal‐and reagent‐free arylation of benzothiophenes by dehydrogenative electrosynthesis

S Lips, D Schollmeyer, R Franke… - Angewandte Chemie …, 2018 - Wiley Online Library
A novel strategy for the synthesis of biaryls consisting of a benzothiophene and a phenol
moiety is reported. These heterobiaryls are of utmost interest for pharmaceutical, biological …

Silver-catalyzed double-decarboxylative cross-coupling of α-keto acids with cinnamic acids in water: a strategy for the preparation of chalcones

N Zhang, D Yang, W Wei, L Yuan, F Nie… - The Journal of …, 2015 - ACS Publications
A silver-catalyzed double-decarboxylative protocol has been proposed for the construction
of chalcone derivatives via cascade coupling of substituted α-keto acids with cinnamic acids …

Hypervalent iodine mediated oxidative cyclization of o-hydroxystilbenes into benzo-and naphthofurans

FV Singh, T Wirth - Synthesis, 2012 - thieme-connect.com
A new and convenient metal-free cyclization of ortho-hydroxystilbenes into 2-
arylbenzofurans and 2-arylnaphthofurans mediated by hypervalent iodine reagents is …

A pincer ruthenium complex for regioselective C–H silylation of heteroarenes

H Fang, L Guo, Y Zhang, W Yao, Z Huang - Organic letters, 2016 - ACS Publications
A pincer Ru (II) catalyst for the highly efficient undirected silylation of O-and S-heteroarenes
with (TMSO) 2MeSiH and Et3SiH is described, producing heteroarylsilanes with exclusive …

Copper-catalyzed Markovnikov hydration of alkynes

M Hassam, WS Li - Tetrahedron, 2015 - Elsevier
Conventional, highly efficient, inexpensive copper triflate catalyzed regioselective
Markovnikov hydration of terminal and internal alkynes have been reported. Significant …