[HTML][HTML] Modelling sorption and transport of gases in polymeric membranes across different scales: a review

E Ricci, M Minelli, MG De Angelis - Membranes, 2022 - mdpi.com
Professor Giulio C. Sarti has provided outstanding contributions to the modelling of fluid
sorption and transport in polymeric materials, with a special eye on industrial applications …

A view on the future of applied thermodynamics

JC De Hemptinne, GM Kontogeorgis… - Industrial & …, 2022 - ACS Publications
Thermodynamics is the science of the interactions between energy and matter. It was
formalized in the late 19th century and remains an essential piece in solving many …

[HTML][HTML] Exploring the membrane-based separation of CO2/CO mixtures for CO2 capture and utilisation processes: Challenges and opportunities

R Checchetto, MG De Angelis, M Minelli - Separation and Purification …, 2024 - Elsevier
The separation and removal of CO 2 from its mixtures with CO is gaining increasing interest
due to the novel processes in which these two gases are mixed, such as the non-thermal …

Cooperativity in Sorption Isotherms

S Shimizu, N Matubayasi - Langmuir, 2023 - ACS Publications
We present a general theory of cooperativity in sorption isotherms that can be applied to
sorbent/gas and sorbent/solution isotherms and is valid even when sorbates dissolve into or …

Glassy polymers: Historical findings, membrane applications, and unresolved questions regarding physical aging

MM Merrick, R Sujanani, BD Freeman - Polymer, 2020 - Elsevier
Polymers below their glass transition temperature (T g) are non-equilibrium glasses
because excess free volume “frozen” between kinetically-restricted polymer chains slowly …

Competitive sorption in CO2/CH4 separations: The case of HAB-6FDA polyimide and its TR derivative and a general analysis of its impact on the selectivity of glassy …

E Ricci, FM Benedetti, ME Dose, MG De Angelis… - Journal of Membrane …, 2020 - Elsevier
CO 2 and CH 4 mixed-gas solubility was measured in 3, 3′-dihydroxy-4, 4′-diamino-
biphenyl (HAB) 2, 2′-bis-(3, 4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA) …

[HTML][HTML] Water sorption in glassy polyvinylpyrrolidone-based polymers

D Borrmann, A Danzer, G Sadowski - Membranes, 2022 - mdpi.com
Polyvinylpyrrolidone (PVP)-based polymers are excellent stabilizers for food supplements
and pharmaceutical ingredients. However, they are highly hygroscopic. This study …

Weak interactions between poly (ether imide) and carbon dioxide: a multiscale investigation combining experiments, theory, and simulations

G Scherillo, G Mensitieri, A Baldanza, V Loianno… - …, 2022 - ACS Publications
This contribution aims at an understanding, at a molecular scale, of the state of CO2
molecules absorbed in glassy poly (ether imide)(PEI). This issue has been challenged by …

Organic solvent reverse osmosis separations of hydrocarbon-alcohol mixtures using matrimid membranes

BD Marshall, JR Johnson, YJ Lee, D Moser… - Journal of Membrane …, 2024 - Elsevier
The organic solvent reverse osmosis (OSRO) separation of alcohol-hydrocarbon mixtures
with Matrimid membranes is studied via experiment as well as modelling with dry glass …

Water sorption in rubbery and glassy polymers, nifedipine, and their ASDs

B Gronniger, E Fritschka, I Fahrig, A Danzer… - Molecular …, 2023 - ACS Publications
Polymers like poly (vinylpyrrolidone-co-vinyl acetate)(PVPVA) or hydroxypropyl
methylcellulose acetate succinate (HPMCAS) are commonly used as a matrix for amorphous …