Mechanochemical tools for polymer materials

Y Chen, G Mellot, D van Luijk, C Creton… - Chemical Society …, 2021 - pubs.rsc.org
Mechanochemistry provides a unique approach to investigate macroscopic deformation,
failure and healing of polymer materials. The development of mechanophores–molecular …

Polymer mechanochromism from force-tuned excited-state intramolecular proton transfer

H Hu, X Cheng, Z Ma, RP Sijbesma… - Journal of the American …, 2022 - ACS Publications
Real-time monitoring of strain/stress in polymers is a big challenge to date. Herein, we for
the first time report an ESIPT (excited-state intramolecular proton transfer)-based …

From force-responsive molecules to quantifying and mapping stresses in soft materials

Y Chen, CJ Yeh, Y Qi, R Long, C Creton - Science advances, 2020 - science.org
Directly quantifying a spatially varying stress in soft materials is currently a great challenge.
We propose a method to do that by detecting a change in visible light absorption. We …

A statistical mechanics framework for polymer chain scission, based on the concepts of distorted bond potential and asymptotic matching

J Mulderrig, B Talamini, N Bouklas - Journal of the Mechanics and Physics …, 2023 - Elsevier
To design increasingly tough, resilient, and fatigue-resistant elastomers and hydrogels, the
relationship between controllable network parameters at the molecular level (bond type, non …

Spirolactam and ESIPT in a Double-Network Elastomer: Multicolor Mechanochromism and Dual-Ratiometric Strain Sensing in Low and High Tensile Stress

H Hu, X Cheng, Y Wu, M Chen, Z Ma, Q Yang… - …, 2024 - ACS Publications
Monitoring strain/stress in the bulk polymer material by mechanochromic mechanophores
(MMs) with multimodal analyses can provide valuable information under loading. Herein …

Molecular damage detection in an elastomer nanocomposite with a coumarin dimer mechanophore

Y Zhang, E Lund, GR Gossweiler, B Lee… - Macromolecular …, 2021 - Wiley Online Library
Molecular force probes that generate optical responses to critical levels of mechanical stress
(mechanochromophores) are increasingly attractive tools for identifying molecular sites that …

A Versatile Benzimidazole-Substituted Spirolactam Mechanophore: When Excited State Intramolecular Proton Transfer Couples with Rhodamine

H Hu, X Cheng, Z Ma, Q Yang, RP Sijbesma… - CCS …, 2024 - chinesechemsoc.org
Exploration of multicolor mechanochromic bulk polymers based on a single mechanophore
is a big challenge to date. Herein, we report a versatile benzimidazole-substituted …

A two-step baromechanical cycle for repeated activation and deactivation of mechanophores

S Kumar, F Zeller, T Stauch - The Journal of Physical Chemistry …, 2021 - ACS Publications
Mechanophores that are embedded in a polymer backbone respond to the application of
mechanical stretching forces by geometric changes such as bond rupture. Typically, these …

Mechanochemical Activation of Red-Light-Excited Triplet–Triplet Annihilation Photon Upconversion

C Broschinski, F Majer, S He… - ACS Applied Optical …, 2024 - ACS Publications
Optical force probes (OFPs) are mechanochemically latent sensors that visualize stress and
strain at the molecular level by changing their optical properties upon force-induced bond …

The activation efficiency of mechanophores can be modulated by adjacent polymer composition

S Kumar, T Stauch - RSC advances, 2021 - pubs.rsc.org
The activation efficiency of mechanophores in stress-responsive polymers is generally
limited by the competing process of unspecific scission in other parts of the polymer chain …