Mechanochemical tools for polymer materials
Mechanochemistry provides a unique approach to investigate macroscopic deformation,
failure and healing of polymer materials. The development of mechanophores–molecular …
failure and healing of polymer materials. The development of mechanophores–molecular …
Polymer mechanochromism from force-tuned excited-state intramolecular proton transfer
Real-time monitoring of strain/stress in polymers is a big challenge to date. Herein, we for
the first time report an ESIPT (excited-state intramolecular proton transfer)-based …
the first time report an ESIPT (excited-state intramolecular proton transfer)-based …
From force-responsive molecules to quantifying and mapping stresses in soft materials
Directly quantifying a spatially varying stress in soft materials is currently a great challenge.
We propose a method to do that by detecting a change in visible light absorption. We …
We propose a method to do that by detecting a change in visible light absorption. We …
A statistical mechanics framework for polymer chain scission, based on the concepts of distorted bond potential and asymptotic matching
To design increasingly tough, resilient, and fatigue-resistant elastomers and hydrogels, the
relationship between controllable network parameters at the molecular level (bond type, non …
relationship between controllable network parameters at the molecular level (bond type, non …
Spirolactam and ESIPT in a Double-Network Elastomer: Multicolor Mechanochromism and Dual-Ratiometric Strain Sensing in Low and High Tensile Stress
Monitoring strain/stress in the bulk polymer material by mechanochromic mechanophores
(MMs) with multimodal analyses can provide valuable information under loading. Herein …
(MMs) with multimodal analyses can provide valuable information under loading. Herein …
Molecular damage detection in an elastomer nanocomposite with a coumarin dimer mechanophore
Y Zhang, E Lund, GR Gossweiler, B Lee… - Macromolecular …, 2021 - Wiley Online Library
Molecular force probes that generate optical responses to critical levels of mechanical stress
(mechanochromophores) are increasingly attractive tools for identifying molecular sites that …
(mechanochromophores) are increasingly attractive tools for identifying molecular sites that …
A Versatile Benzimidazole-Substituted Spirolactam Mechanophore: When Excited State Intramolecular Proton Transfer Couples with Rhodamine
Exploration of multicolor mechanochromic bulk polymers based on a single mechanophore
is a big challenge to date. Herein, we report a versatile benzimidazole-substituted …
is a big challenge to date. Herein, we report a versatile benzimidazole-substituted …
A two-step baromechanical cycle for repeated activation and deactivation of mechanophores
Mechanophores that are embedded in a polymer backbone respond to the application of
mechanical stretching forces by geometric changes such as bond rupture. Typically, these …
mechanical stretching forces by geometric changes such as bond rupture. Typically, these …
Mechanochemical Activation of Red-Light-Excited Triplet–Triplet Annihilation Photon Upconversion
C Broschinski, F Majer, S He… - ACS Applied Optical …, 2024 - ACS Publications
Optical force probes (OFPs) are mechanochemically latent sensors that visualize stress and
strain at the molecular level by changing their optical properties upon force-induced bond …
strain at the molecular level by changing their optical properties upon force-induced bond …
The activation efficiency of mechanophores can be modulated by adjacent polymer composition
The activation efficiency of mechanophores in stress-responsive polymers is generally
limited by the competing process of unspecific scission in other parts of the polymer chain …
limited by the competing process of unspecific scission in other parts of the polymer chain …