Combining spectroscopic and transient kinetic techniques provides access to the
identification and quantification of active sites and corresponding turnover frequencies of …

The state-of-the-art in the theory of routes for multi-route reactions in the homogeneous
catalysis with metal complexes is reviewed. Key problems and the possible approaches to …

The reaction of α-olefin hydroalumination by alkylalanes HAlBu 2 i, ClAlBu 2 i, AlBu 3 i
catalyzed by Cp 2 ZrCl 2 was studied. The kinetic model for the reaction steps isolated from …

New theoretical relationships for a complex catalytic reaction accompanied by deactivation
are obtained, using as an example the two-step catalytic mechanism (Temkin–Boudart …

The exact autonomous (time-independent) kinetic invariants of nonlinear chemical reactions
occurring in open systems with the participation of an independent and any number of …

New linear concentration and temperature conservation laws have been found for chemical
reactions that proceed according to nonlinear mechanisms in an open nonisothermal perfect …

The possibility of the existence of a multiset of stationary states of a kinetic nature in the
simplest two-stage catalytic reaction according to Temkin, which proceeds according to the …

Abstract Alkyl 1 H-pyrrole-2-carboxylates and dialkyl 1 H-pyrrole-2, 5-dicarboxylates were
synthesized in quantitative yield by reactions of 1 H-pyrrole, 2-acetyl-1 H-pyrrole, and 1 …

Mathematical models of nonequilibrium processes in distributed systems are described by
partial differential equations with given boundary conditions and, as a rule, cannot be solved …

A method for solving the inverse problem of chemical kinetics based on the data of non-
stationary experiments for multistage reactions is described. The method is based on the …