Dynamics of polymer segments, polymer chains, and nanoparticles in polymer nanocomposite melts: A review

EJ Bailey, KI Winey - Progress in Polymer Science, 2020 - Elsevier
The addition of nanoparticles (NPs) to a polymer matrix, forming a polymer nanocomposite
(PNC), is known to alter the microscopic dynamic processes of both species which leads to …

Interphase in polymer nanocomposites

J Huang, J Zhou, M Liu - JACS Au, 2022 - ACS Publications
The lightweight and high-strength functional nanocomposites are important in many
practical applications. Natural biomaterials with excellent mechanical properties provide …

50th Anniversary Perspective: Are Polymer Nanocomposites Practical for Applications?

SK Kumar, BC Benicewicz, RA Vaia, KI Winey - Macromolecules, 2017 - ACS Publications
The field of polymer nanocomposites has been at the forefront of research in the polymer
community for the past few decades. Foundational work published in Macromolecules …

Concepts and conflicts in nanoparticles reinforcement to polymers beyond hydrodynamics

Y Song, Q Zheng - Progress in Materials Science, 2016 - Elsevier
With substantial progresses in reinforcement mechanism of nanoparticle filled polymers
(NPFPs) beyond the hydrodynamic limit, now is the time to reconsider this topic …

Big effect of small nanoparticles: a shift in paradigm for polymer nanocomposites

S Cheng, SJ Xie, JMY Carrillo, B Carroll, H Martin… - ACS …, 2017 - ACS Publications
Polymer nanocomposites (PNCs) are important materials that are widely used in many
current technologies and potentially have broader applications in the future due to their …

[HTML][HTML] Perspective: Outstanding theoretical questions in polymer-nanoparticle hybrids

SK Kumar, V Ganesan, RA Riggleman - The Journal of chemical …, 2017 - pubs.aip.org
This topical review discusses the theoretical progress made in the field of polymer
nanocomposites, ie, hybrid materials created by mixing (typically inorganic) nanoparticles …

Structural analyses of the bound rubber in silica-filled silicone rubber nanocomposites reveal mechanisms of filler-rubber interaction

L Huang, F Yu, Y Liu, A Lu, Z Song, W Liu… - … Science and Technology, 2023 - Elsevier
Although the reinforcing effect of fumed silica on silicone rubber is always better than that of
precipitated silica, their enhancement mechanism is still controversial due to the cognitive …

[HTML][HTML] Defects and defect engineering in Soft Matter

A Jangizehi, F Schmid, P Besenius, K Kremer… - Soft Matter, 2020 - pubs.rsc.org
Soft matter covers a wide range of materials based on linear or branched polymers, gels and
rubbers, amphiphilic (macro) molecules, colloids, and self-assembled structures. These …

Interfacial properties of polymer nanocomposites: Role of chain rigidity and dynamic heterogeneity length scale

S Cheng, B Carroll, W Lu, F Fan, JMY Carrillo… - …, 2017 - ACS Publications
While it is known that the properties of polymer nanocomposites are largely dominated by
the interfacial layer around nanoparticles, the molecular parameters controlling the …

[HTML][HTML] Focus: Structure and dynamics of the interfacial layer in polymer nanocomposites with attractive interactions

S Cheng, B Carroll, V Bocharova, JM Carrillo… - The Journal of …, 2017 - pubs.aip.org
In recent years it has become clear that the interfacial layer formed around nanoparticles in
polymer nanocomposites (PNCs) is critical for controlling their macroscopic properties. The …