Cobalt-catalyzed hydroformylation of alkenes: generation and recycling of the carbonyl species, and catalytic cycle

F Hebrard, P Kalck - Chemical Reviews, 2009 - ACS Publications
In1938, whileOttoRoelenwasstudyingtheFischer-Tropsch reaction, which converts H2/CO
into alkanes and alkenes, and was trying to improve the yields by recycling ethylene, the …

Three characteristic reactions of organocobalt compounds in organic synthesis

I Omae - Applied Organometallic Chemistry, 2007 - Wiley Online Library
Organocobalt compounds in organic synthesis have three characteristic reactions. The first
occurs because cobalt has a high affinity to carbon–carbon π‐bonds or carbon–nitrogen π …

Solvents from nature

IT Horváth - Green Chemistry, 2008 - pubs.rsc.org
In this perspective, a personal journey from solvent to solvent is presented to demonstrate
how environmentally friendly solvents can be part of the solution of various chemical …

Palladium-catalyzed 3,4-hydroaminocarbonylation of conjugated dienes for formation of β,γ-unsaturated amides

HY Yang, LQ Lin, NQ Li, ZH Ren, ZH Guan - Science China Chemistry, 2023 - Springer
Hydrocarbonylation of conjugated dienes is one of the most promising yet challenging
methods for the synthesis of carbonyl compounds. Herein, we reported the development of …

Molybdenum disulfide promoted co-catalyzed alkoxycarbonylation

Z Zheng, H Zhou, L Deng, X Jia, Y Li - Journal of Catalysis, 2024 - Elsevier
Herein, we presented a novel approach involving molybdenum disulfide (MoS 2) promoted
in-situ generation of active cobalt catalyst for alkoxycarbonylation reaction, an industrial …

Cobalt-catalysed hydroformylation of epoxides in the presence of phosphine oxides

FG Delolo, C Kubis, B Zhang, H Neumann… - Catalysis Science & …, 2024 - pubs.rsc.org
A novel cobalt-catalysed hydroformylation of epoxides to β-hydroxyaldehydes was
developed. Compared to previous works this methodology proceeds under significantly …

Palladium-catalyzed methoxycarbonylation of 1, 3-butadiene to methyl-3-pentenoate: Introduction of a continuous process

LJ Han, CS Rao, SS Ma, GY Sheng, JP Zhang… - Journal of Catalysis, 2021 - Elsevier
The base-assisted Pd (cod) Cl 2/Xantphos-catalyzed methoxycarbonylation of 1, 3-
butadiene (BD) to methyl-3-pentenoate (MP) was explored. Mechanistic studies suggest the …

Mechanistic investigations of a bifunctional squaramide organocatalyst in asymmetric Michael reaction and observation of stereoselective retro-Michael reaction

E Varga, LT Mika, A Csámpai, T Holczbauer… - RSC …, 2015 - pubs.rsc.org
The mechanism of the addition of acetylacetone to β-nitrostyrene catalyzed by a cinchona
based squaramide catalyst was studied in detail under synthetically relevant conditions. The …

[HTML][HTML] Efficient methoxycarbonylation of diisobutylene over functionalized ZSM-5 supported cobalt complex catalysts

F Jin, J Wang, H Song, Z Quan, Q Liu, Y Yan… - Arabian Journal of …, 2023 - Elsevier
By grafting nitrogen-containing complexes onto ZSM-5 mesoporous material and then
supporting a cobalt catalyst in situ, the methoxycarbonylation of diisobutylene (DIB) was …

Production of platform molecules from sweet sorghum

G Novodárszki, N Rétfalvi, G Dibó, P Mizsey… - RSC …, 2014 - pubs.rsc.org
This study proves that the non-food dedicated sweet sorghum (Sorghum bicolor) can be a
possible source and/or raw material of platform molecules such as levulinic acid (LA) and 5 …