Molecular Magnets: The Synthesis and Characterization of High‐Spin Nitrenes

SV Chapyshev, E Mendez‐Vega… - Chemistry–A European …, 2021 - Wiley Online Library
Abstract Among all C‐, N‐, and O‐centered polyradicals, high‐spin nitrenes possess the
largest magnetic anisotropy and are of considerable interest as multi‐level molecular spin …

Electronic structures of aromatic hydrocarbons with high spin multiplicities in the electronic ground state

K Itoh - Pure and Applied Chemistry 26th, 1978 - degruyter.com
It has been established experimentally that there are alternant hydrocarbons (AH) with high
spin multiplicities in the electr~ pic ground state, the highest multiplicity known up to date …

Recent advances in chemistry of high-spin nitrenes

SV Chapyshev, DV Korchagin… - Russian Chemical …, 2021 - iopscience.iop.org
Experimental and theoretical studies on aromatic nitrenes bearing from three to six unpaired
electrons and having quartet, quintet, sextet or septet ground spin states, published in the …

Nitrogen‐Rich Salts Based on Energetic Nitroaminodiazido [1, 3, 5] triazine and Guanazine

Y Huang, Y Zhang, JM Shreeve - Chemistry–A European …, 2011 - Wiley Online Library
Highly dense nitrogen‐rich ionic compounds are potential high‐performance energetic
materials for use in military and industrial venues. Guanazinium salts with promising …

Crystal Packing of Planar Organic Azide Molecules

K Xue, C Zuo, S Guo, S Zhang… - Crystal Growth & Design, 2024 - ACS Publications
Organic azides possess the potential for green primary explosives, gas generators, and
propellants. This work focuses on the crystal packing of 34 planar organic azides and …

Stable Room Temperature Nitrenes Created by Photolysis of Crystalline 4-Azido-2, 3, 5, 6-tetrafluorobenzoic Acid

TJ Gately, RA Boto, MJ Tauber… - The Journal of …, 2023 - ACS Publications
The structure, spectroscopy, and photochemistry of 4-azidobenzoic acid (4ABC) and its
perfluorinated analog 4-azido-2, 3, 5, 6-tetrafluorobenzoic acid (4F4ABC) are characterized …

Aromatic polyazides and high-spin nitrenes

SV Chapyshev - Russian Chemical Bulletin, 2011 - Springer
Aromatic polyazides are widely used as starting compounds in organic synthesis and for
preparation of nitrogen—carbon nanomaterials and high-spin nitrenes. The latter have the …

Silver Salt of 4,6‐Diazido‐N‐nitro‐1,3,5‐triazine‐2‐amine – Characterization of this Primary Explosive

T Musil, R Matyáš, R Vala, A Růžička… - Propellants …, 2014 - Wiley Online Library
A new primary explosive, the silver salt of 4, 6‐diazido‐N‐nitro‐1, 3, 5‐triazine‐2‐amine
(AgDANT), was synthesized and characterized. AgDANT was prepared with a 97% yield …

Selective reactions on the azido groups of aromatic polyazides

SV Chapyshev - Synlett, 2009 - thieme-connect.com
Aromatic azides are widely used as starting materials in organic synthesis and as
photoaffinity labeling reagents in molecular biology. When aromatic azides have two or …

Tandem deprotonation/azide–tetrazole tautomerization of 4, 6-diazido-N-nitro-1, 3, 5-triazin-2-amine in dimethylsulfoxide solutions: a theoretical study

SV Chapyshev, EN Ushakov - Physical Chemistry Chemical Physics, 2015 - pubs.rsc.org
4, 6-Diazido-N-nitro-1, 3, 5-triazin-2-amine (2) is a new promising high-energy organic
compound that isomerizes in dimethylsulfoxide (DMSO) solutions to form unknown products …