Phenalenyl, a zigzag-edged odd alternant hydrocarbon unit can be found in the graphene
nanosheet. Hückel molecular orbital calculations indicate the presence of a nonbonding …

Conspectus The odd alternant hydrocarbon phenalenyl (PLY) can exist in three different
forms, a closed-shell cation, an open-shell radical, and a closed-shell anion, using its …

Herein, we have established a phenalenyl-based molecular scaffold which serves as a
potent photoreductant utilizing the empty NBMO in the presence of a base to form a radical …

In this report, a ligand-redox assisted catalytic hydrosilylation has been investigated. A
phenalenyl ligand coordinated nickel complex has been utilized as an electron reservoir to …

Abstract The lithiation of 1, 3‐dipropoxy‐p‐tert‐butylcalix [4] arene (LH2) followed by
reaction with nBuMgBr in THF resulted in the formation of the hetero‐bimetallic complex [Li …

Zr (IV) complexes containing salan-type diamine bis (phenolato) ligands were synthesized
and characterized by various spectroscopic techniques and X-ray crystallography. We …

We have demonstrated that the nonbonding molecular orbital (NBMO) of the phenalenyl
(PLY) cation can be used as a Lewis acid catalyst for different organic transformations …

This perspective review discusses metallocalix [n] arene complexes that have been
employed in either α-olefin polymerization or in the ring opening polymerization (ROP) of …

Open-shell phenalenyl chemistry has widely been explored in the last five decades
demonstrating its potential in various applications including molecular switch, spin memory …

Abnormal N-heterocyclic carbene (aNHC) adducts of zinc (II)(1) and aluminum (III)(2) were
synthesized. The compounds were characterized by NMR spectroscopy and elemental …