Pincer complexes in photo-and electro-catalytic hydrogen evolution (HER) and carbon dioxide reduction reactions (CO2RR)

MAW Lawrence, C Thompson, SC Lorraine - Inorganica Chimica Acta, 2024 - Elsevier
Pincer complexes have aided in the understanding of a number of processes mediated by
transition metal compounds. In homogenous catalytic transformations, pincers as ligands …

Recent advances in spectroelectrochemistry related to molecular catalytic processes

CW Machan - Current Opinion in Electrochemistry, 2019 - Elsevier
Continuing interest in renewable energy utilization, the depletion of nonrenewable
petrochemical feedstocks and rising atmospheric concentrations of CO 2 from …

Voltammetric properties and applications of hydrazones and azo moieties

MAW Lawrence, SC Lorraine, KA Wilson, K Wilson - Polyhedron, 2019 - Elsevier
Hydrazones and azo compounds have been actively studied for more than a century, with
thousands of papers presented in the literature. Both functional groups allow for facile …

Cis and trans-palladium (II) complexes derived from SNN amidrazone pincer ligand: Synthesis, crystal structures and biological evaluation

M Al-Noaimi, FF Awwadi, WH Talib, S Atia… - Journal of Molecular …, 2019 - Elsevier
Abstract Palladium (II) complex [Pd (HL) Cl](1)(H 2 L= 2-PhS (C 6 H 4) NH-NC=(COCH 3)–
NHC 6 H 5) has been synthesized by reacting K 2 PdCl 4 with H 2 L. The pincer H 2 L ligand …

Effect of chalcogen bonding interactions on molecular structures; theoretical and crystallographic studies on two palladium (II) acetate complexes

M Al-Noaimi, FF Awwadi, A Hendal… - New Journal of …, 2022 - pubs.rsc.org
Two palladium complexes,[Pd (L1)(OAc))](1) and [Pd (L2)(OAc))](2), have been synthesized
by reacting Pd (OAc) 2 and new thioetherazo (HL) ligands (HL= 2 (RS) C6H4NH–NC …

Electrochemical response of a Ru (II) benzothiazolyl-2-pyridinecarbothioamide pincer towards carbon dioxide and transfer hydrogenation of aryl ketones in air

SC Lorraine, MAW Lawrence, M Celestine… - Journal of Molecular …, 2020 - Elsevier
A ruthenium (II) complex of 6-(4, 7-dimethoxy-2-benzothiazolyl)-N-(2, 5-dimethoxyphenyl)-2-
pyridinecarbothioamide (pbcta), of the formula [Ru (pbcta) Cl 2 (dmf)](1, where DMF …

Catalytic C–C cross-coupling and hydrogen evolution by two Pd (II)-complexes of di-2-pyridyl ketone benzoyl hydrazones

M Bakir, MW Lawrence, P Nelson… - Journal of Coordination …, 2019 - Taylor & Francis
The reactions between [PdCl2 (CH3CN) 2] and dpk-h [dpk-h= di-2-pyridyl ketone benzoyl
hydrazone (dpkbh) or di-2-pyridyl ketone 4-aminobenzoyl hydrazone (dpk-4-abh)] at room …

Assessment of two cobalt (II) complexes with pincer ligands for the electrocatalytic hydrogen evolution reaction. A comparison of the SNS vs ONS coordination

MAW Lawrence, WH Mulder, MJ Celestine… - Inorganica Chimica …, 2020 - Elsevier
Abstract Bis-N-(2, 5-dimethoxyphenyl) pyridine-2, 6-dicarbothioamide (pdcta) and N-(2, 5-
dimethoxyphenyl)-6-[(2, 5-dimethoxyphenyl) carbamothioyl] pyridine-2-carboxamide (pcta) …

Catalysis by Pincer Compounds and Their Contribution to Environmental and Sustainable Processes

H Valdés, D Morales‐Morales - Catalysis for a Sustainable …, 2024 - Wiley Online Library
This chapter presents the role that pincer compounds have played in the development of
sustainable catalytic processes based on the use of catalytic transformations promoted by …

N-substituted 2-pyridinecarbothioamides and polypyridyl mixed-ligand cobalt (III)-containing complexes for photocatalytic hydrogen generation

MJ Celestine, MAW Lawrence, NK Evaristo… - Inorganica Chimica …, 2020 - Elsevier
Two mixed-ligand cobalt (III) complexes containing 2, 2′-bipyridine (bpy) or 1, 10-
phenanthroline (phen), and N-(3, 5-bis (trifluoromethyl) phenyl) pyridine-2-carbothioamide …