Catalytic transformation of CO 2 into C1 chemicals using hydrosilanes as a reducing agent

Y Zhang, T Zhang, S Das - Green Chemistry, 2020 - pubs.rsc.org
Utilization of CO2 for the synthesis of fine chemicals and pharmaceuticals has attracted
tremendous attention. In fact, reductive transformation of CO2 is also an interesting …

Advancements and challenges in reductive conversion of carbon dioxide via thermo-/photocatalysis

LQ Qiu, X Yao, YK Zhang, HR Li… - The Journal of Organic …, 2022 - ACS Publications
Carbon dioxide (CO2) is the major greenhouse gas and also an abundant and renewable
carbon resource. Therefore, its chemical conversion and utilization are of great attraction for …

Covalent organic framework-supported Zn single atom catalyst for highly efficient N-formylation of amines with CO2 under mild conditions

Q Cao, LL Zhang, C Zhou, JH He, A Marcomini… - Applied Catalysis B …, 2021 - Elsevier
Transformation of CO 2 into value-added chemicals with efficient and recyclable catalyst is
an effective way to reduce carbon emissions. It is valuable to develop an efficient catalyst …

Biomass-derived N-doped porous carbon: an efficient metal-free catalyst for methylation of amines with CO 2

F Tang, L Wang, YN Liu - Green Chemistry, 2019 - pubs.rsc.org
Developing green, efficient, and low-cost catalysts for methylation of N–H by using CO2 as
the C1 resource is highly desired yet remains a significant challenge. Herein, N-doped …

Selective N-formylation/N-methylation of amines and N-formylation of amides and carbamates with carbon dioxide and hydrosilanes: promotion of the basic counter …

Q Zhang, XT Lin, N Fukaya, T Fujitani, K Sato… - Green …, 2020 - pubs.rsc.org
A catalyst composed of commercially available Zn (OAc) 2 and 1, 10-phenanthroline (phen)
was effective in the N-formylation/N-methylation of amines using CO2 as the C1 source in …

Sodium triethylborohydride-catalyzed controlled reduction of unactivated amides to secondary or tertiary amines

W Yao, L He, D Han, A Zhong - The Journal of Organic Chemistry, 2019 - ACS Publications
The first transition-metal-free catalytic protocol for controlled reduction of amide functions
using cheap and bench-stable hydrosilanes as reducing agents has been established. By …

A sustainable strategy for the visible-light-driven facile N-formylation of amines using a Co (ii)-embedded covalent organic framework as an efficient photocatalyst

S Das, P Sarkar, M Goswami, SM Ali… - Materials Chemistry …, 2023 - pubs.rsc.org
Nowadays, to tackle the increased greenhouse effect, the development of efficient porous
adsorbents with the capacity for rapid atmospheric CO2 uptake is one of the new concerns …

Unexpected Macrocyclic Multinuclear Zinc and Nickel Complexes that Function as Multitasking Catalysts for CO2 Fixations

K Takaishi, BD Nath, Y Yamada, H Kosugi… - Angewandte …, 2019 - Wiley Online Library
Unique self‐assembled macrocyclic multinuclear ZnII and NiII complexes with binaphthyl‐
bipyridyl ligands (L) were synthesized. X‐ray analysis revealed that these complexes …

Mn‐Catalyzed Selective Double and Mono‐N‐Formylation and N‐Methylation of Amines by using CO2

Z Huang, X Jiang, S Zhou, P Yang, CX Du… - …, 2019 - Wiley Online Library
Functionalization of amines by using CO2 is of fundamental importance considering the
abundance of amines and CO2. In this context, the catalytic formylation and methylation of …

Mesoionic N-heterocyclic olefin catalysed reductive functionalization of CO 2 for consecutive N-methylation of amines

S Maji, A Das, SK Mandal - Chemical Science, 2021 - pubs.rsc.org
A mesoionic N-heterocyclic olefin (mNHO) was introduced as a metal-free catalyst for the
reductive functionalization of CO2 leading to consecutive double N-methylation of primary …