Role of Coordination Number and Geometry in Controlling the Magnetic Anisotropy in FeII, CoII, and NiII Single‐Ion Magnets
Since the last decade, the focus in the area of single‐molecule magnets (SMMs) has been
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
Structures and Properties of a Series of High-Spin [CoII2] Complexes Supported by Ancillary Benzoate, Ortho-Hydroxybenzoate, and Para-Hydroxybenzoate …
A new series of high-spin [CoII2] complexes [Co2 (cpdp)(μ-O2CC6H5)](1),[Co2 (cpdp)(μ-o-
O2CC6H4 (OH))]· H2O (2), and [Co2 (cpdp)(μ-p-O2CC6H4 (OH))]· 5H2O (3) of the …
O2CC6H4 (OH))]· H2O (2), and [Co2 (cpdp)(μ-p-O2CC6H4 (OH))]· 5H2O (3) of the …
Pentagonal Bipyramid FeII Complexes: Robust Ising‐Spin Units towards Heteropolynuclear Nanomagnets
Pentagonal bipyramid FeII complexes have been investigated to evaluate their potential as
Ising‐spin building units for the preparation of heteropolynuclear complexes that are likely to …
Ising‐spin building units for the preparation of heteropolynuclear complexes that are likely to …
Tuning chain topologies and magnetic anisotropy in one-dimensional cobalt (II) coordination polymers via distinct dicarboxylates
Based on a terpyridine derivative and two different dicarboxylate ligands, two new cobalt (II)
coordination polymers, namely [Co (pytpy)(DClbdc)] n (1) and [Co (pytpy)(ndc)] n (2)(pytpy …
coordination polymers, namely [Co (pytpy)(DClbdc)] n (1) and [Co (pytpy)(ndc)] n (2)(pytpy …
Structure-property correlation in stabilizing axial magnetic anisotropy in octahedral Co (II) complexes
Stabilizing an easy axis of magnetization in an octahedral Co (II) complex is an extremely
challenging task, which is evident from reports that more than 90% possess easy-plane …
challenging task, which is evident from reports that more than 90% possess easy-plane …
[HTML][HTML] General framework for calculating spin–orbit couplings using spinless one-particle density matrices: Theory and application to the equation-of-motion coupled …
Standard implementations of nonrelativistic excited-state calculations compute only one
component of spin multiplets (ie, M s= 0 triplets); however, matrix elements for all …
component of spin multiplets (ie, M s= 0 triplets); however, matrix elements for all …
Progress towards creating optically addressable molecular qubits
MS Fataftah, DE Freedman - Chemical Communications, 2018 - pubs.rsc.org
The emerging field of quantum information science promises to transform a diverse range of
scientific fields, ranging from computation to sensing and metrology. The interdisciplinary …
scientific fields, ranging from computation to sensing and metrology. The interdisciplinary …
Structural dependence of the ising-type magnetic anisotropy and of the relaxation time in mononuclear trigonal bipyramidal Co (II) single molecule magnets
This paper describes the correlation between Ising-type magnetic anisotropy and structure
in trigonal bipyramidal Co (II) complexes. Three sulfur-containing trigonal bipyramidal Co (II) …
in trigonal bipyramidal Co (II) complexes. Three sulfur-containing trigonal bipyramidal Co (II) …
On balancing the QTM and the direct relaxation processes in single-ion magnets–the importance of symmetry control
YF Deng, T Han, B Yin, YZ Zheng - Inorganic Chemistry Frontiers, 2017 - pubs.rsc.org
Two mononuclear trigonal-planar Co (II) complexes [Na (THF) 6][Co (OAr) 3] 1 and [(THF)
3NaCo (OAr) 3] 2 (OAr−= 2, 6-di-tert-butylphenoxo, THF= tetrahydrofuran) with the same …
3NaCo (OAr) 3] 2 (OAr−= 2, 6-di-tert-butylphenoxo, THF= tetrahydrofuran) with the same …
Probing the Magnetic Anisotropy of Co (II) Complexes Featuring Redox-Active Ligands
P Kumar, DJ SantaLucia… - Inorganic …, 2020 - ACS Publications
Coordination complexes that possess large magnetic anisotropy (otherwise known as zero-
field splitting, ZFS) have possible applications in the field of magnetic materials, including …
field splitting, ZFS) have possible applications in the field of magnetic materials, including …