Chelation-assisted transition metal-catalysed C–H chalcogenylations

W Ma, N Kaplaneris, X Fang, L Gu, R Mei… - Organic Chemistry …, 2020 - pubs.rsc.org
The development of convenient and mild chalcogenylation reactions for the preparation of
unsymmetrical diaryl sulfides and diaryl selenides has received significant attention in …

A review on the latest progress of C‐S cross‐coupling in diaryl sulfide synthesis: Update from 2012 to 2021

F Abedinifar, S Bahadorikhalili… - Applied …, 2022 - Wiley Online Library
Diaryl sulfides are a highly valuable class of sulfur‐containing compounds presented in
numerous drugs with a broad range of therapeutic activities and are also employed as …

Electrochemical direct C–H mono and bis-chalcogenation of indolizine frameworks under oxidant-free conditions

A Chouhan, K Ucheniya, L Yadav, PK Jat… - Organic & …, 2023 - pubs.rsc.org
Herein, we disclosed a sustainable electrochemical approach for site-selective C–H mono
and bis-chalcogenation (sulfenylation or selenylation) of indolizine frameworks. Diversely …

Electrochemical site-selective direct C–H sulfenylation and selenylation of a chromone-fused-indolizine (CFI) skeleton

PK Jat, L Yadav, A Chouhan, K Ucheniya… - Chemical …, 2023 - pubs.rsc.org
Herein, for the first time, we report the transition metal-free electrochemical site-selective
direct C–H sulfenylation/selenylation of chromone-fused indolizine compounds (CFIs) to …

Metal-and photocatalyst-free synthesis of 3-selenylindoles and asymmetric diarylselenides promoted by visible light

ID Lemir, WD Castro-Godoy, AA Heredia, LC Schmidt… - RSC …, 2019 - pubs.rsc.org
A novel and sustainable procedure was developed for the synthesis of 3-selenylindoles
employing diorganyl diselenides and indoles or electron-rich arenes as starting materials …

[HTML][HTML] Synthesis of perfluoroaryl sulfides at electron-poor arenes via an SNAr step with an unexpected mechanism

HH Liao, SC Lee, H Kao, YL Hsu, CM Hsu… - Cell Reports Physical …, 2022 - cell.com
Perfluoroaryl groups are a recurring motif in materials and pharmaceutical chemistry. Here,
we report a method to couple perfluoroarenes and thiols to yield perfluoroaryl sulfides via a …

B (C6F5) 3-catalyzed selective C–H chalcogenation of arenes and heteroarenes

M Pramanik, S Das, R Babaahmadi, S Pahar, T Wirth… - Chem, 2024 - cell.com
The synthesis of organochalcogenides remains a valuable area of research due to their
widespread biological applications, particularly in pharmaceuticals. Herein, our study details …

Synthesis of Asymmetric Diaryl Sulfides via HI-Mediated C(sp2)-H Sulfenylation of Arenes with Sodium Sulfinates

S Sun, H Ye, T Mao, Y Guo, H Liu, J Li… - The Journal of Organic …, 2023 - ACS Publications
A novel hydroiodic acid-promoted metal-free C (sp2)-H sulfenylation of electron-rich arenes
was developed using stable and easy-to-handle sodium sulfinates as sulfur sources …

Boosted Heterogeneous Catalysis by Surface‐Accumulated Excess Electrons of Non‐Oxidized Bare Copper Nanoparticles on Electride Support

SS Han, A Thacharon, J Kim, K Chung, X Liu… - Advanced …, 2023 - Wiley Online Library
Engineering active sites of metal nanoparticle‐based heterogeneous catalysts is one of the
most prerequisite approaches for the efficient production of chemicals, but the limited active …

Photocatalytic Synthesis of 3‐Sulfanyl‐and 1, 3‐Bis (sulfanyl) indolizines Mediated by Visible Light

F Penteado, CS Gomes, LI Monzon… - European Journal of …, 2020 - Wiley Online Library
A metal‐free method for the synthesis of 3‐sulfanyl indolizines from thiols and 2‐
arylindolizines, is reported. The reaction is mediated by eosin Y under blue LED light …