Catalytic transmetalation from group 6 Fischer carbene complexes: An emerging powerful tool in organic synthesis

M Gómez-Gallego, MJ Mancheño… - Accounts of chemical …, 2005 - ACS Publications
The chemistry of metal carbene complexes has experienced an enormous development in
the past decades. Despite this fact, the use of transition metals as catalysts in reactions …

Fischer carbene complexes: beautiful playgrounds to study single electron transfer (SET) reactions

MA Sierra, M Gómez‐Gallego… - … –A European Journal, 2007 - Wiley Online Library
The knowledge of the reactivity of Fischer carbene complexes in electron transfer processes
is still in the early stage of development, but interesting advances are foreseeable in this …

Recent advances in the field of multicarbene and multimetal carbene complexes of the Fischer-type

DI Bezuidenhout, S Lotz, DC Liles… - Coordination Chemistry …, 2012 - Elsevier
This review article covers the development of Fischer carbene complexes since the year
2000, with specific focus on carbene complexes bearing metal-containing fragments as …

A straightforward synthesis of tetrameric estrone-based macrocycles

P Ramírez-López, MC de la Torre… - Organic …, 2008 - ACS Publications
A straightforward approach to macrocycles having four estrone-derived nuclei by the
sequential Cu-catalyzed Huisgen azide− alkyne cycloaddition− Glaser− Eglington Cu …

Substituent effects on the electrochemical, spectroscopic, and structural properties of fischer mono-and biscarbene complexes of chromium (0)

B Van der Westhuizen, PJ Swarts… - Inorganic …, 2013 - ACS Publications
A series of ten ferrocenyl, furyl, and thienyl mono-and biscarbene chromium (0) complexes
were synthesized and characterized spectroscopically and electrochemically. The single …

Electrochemical illumination of thienyl and ferrocenyl chromium (0) Fischer carbene complexes

B Van der Westhuizen, PJ Swarts, I Strydom… - Dalton …, 2013 - pubs.rsc.org
A series of ferrocenyl and thienyl mono-and biscarbene chromium (0) complexes 1–6 were
synthesised. The complexes were characterised both spectroscopically and …

A Copper-Catalyzed Azide− Alkyne Cycloaddition Approach to the Synthesis of Bimetallic Chromium (0)(Fischer) Carbene Complexes

B Baeza, L Casarrubios, P Ramírez-López… - …, 2009 - ACS Publications
The Cu (I)-catalyzed 1, 3-dipolar cycloaddition of bis-azides to alkynyl chromium (0)(Fischer)
carbene complexes has been developed. The method is a new entry to the synthesis of …

Remote control by π-conjugation of the emissive properties of Fischer carbene-BODIPY dyads

GM Chu, A Guerrero-Martinez… - Inorganic …, 2016 - ACS Publications
The synthesis, structure, and complete characterization of mono-and bimetallic dyads
joining Fischer carbene complexes and BODIPY chromophores are reported. In these …

Synthesis and electrochemical study of iron, chromium and tungsten aminocarbenes: Role of ligand structure and central metal nature

I Hoskovcová, J Roháčová, D Dvořák, T Tobrman… - Electrochimica …, 2010 - Elsevier
Several series of Fischer-type aminocarbene complexes with central Fe, Cr or W atoms and
with various carbene substitution were synthesized and electrochemically investigated by dc …

Metal–metal interaction in Fischer carbene complexes: a study of ferrocenyl and biferrocenyl tungsten alkylidene complexes

B Van der Westhuizen, JM Speck, M Korb… - Inorganic …, 2013 - ACS Publications
A series of ferrocenyl (Fc= ferrocenyl; fc= ferrocen-1, 1′-diyl) and biferrocenyl (Bfc= 1′, 1
″-biferrocenyl; bfc= 1′, 1 ″-biferrocen-1, 1‴-diyl) mono-and biscarbene tungsten (0) …