The mechanochemical synthesis of polymers

A Krusenbaum, S Grätz, GT Tigineh… - Chemical Society …, 2022 - pubs.rsc.org
Mechanochemistry–the utilization of mechanical forces to induce chemical reactions–is a
rarely considered tool for polymer synthesis. It offers numerous advantages such as reduced …

Mechanochemistry for synthesis

T Friščić, C Mottillo, HM Titi - Angewandte Chemie, 2020 - Wiley Online Library
Mechanochemical solvent‐free reactions by milling, grinding or other types of mechanical
action have emerged as a viable alternative to solution chemistry. Mechanochemistry offers …

Tackling solubility issues in organic synthesis: solid-state cross-coupling of insoluble aryl halides

T Seo - Palladium-Catalyzed Mechanochemical Cross …, 2024 - Springer
Conventional organic synthesis generally relies on the use of liquid organic solvents to
dissolve the reactants. Therefore, reactions of sparingly soluble or insoluble substrates are …

Recent advances in the Suzuki–Miyaura cross-coupling reaction using efficient catalysts in eco-friendly media

SE Hooshmand, B Heidari, R Sedghi, RS Varma - Green Chemistry, 2019 - pubs.rsc.org
The ever-increasing interest in the Suzuki–Miyaura cross-coupling reaction (SMR) and its
applications, with more than 40 years of history, has increased exponentially in the last …

Metal-mediated and metal-catalyzed reactions under mechanochemical conditions

A Porcheddu, E Colacino, L De Luca, F Delogu - ACS Catalysis, 2020 - ACS Publications
The extraordinary impact of metal-based complexes on synthetic methods is still recognized
nowadays, and attempts are currently undertaken to further extend the use of metal-assisted …

Mechanochemical cross-coupling reactions

K Kubota, H Ito - Trends in chemistry, 2020 - cell.com
In recent years, solvent-less mechanochemical organic transformations using ball milling
have come to the forefront of organic synthesis as cleaner and sustainable synthetic …

Deep eutectic solvents: Cutting-edge applications in cross-coupling reactions

SE Hooshmand, R Afshari, DJ Ramón, RS Varma - Green Chemistry, 2020 - pubs.rsc.org
Deep eutectic solvents (DESs), surmised as “the organic reaction medium of the century”,
have reverberated a new symphony throughout the present green millennium. A brief …

Progress on entropy production engineering for electrochemical catalysis

X Zhang, K Ren, Y Liu, Z Gu, Z Huang, S Zheng… - Acta Physico-Chimica …, 2024 - Elsevier
As for the accurate synthesis of high-performance electrochemical catalysts with good
robustness, the rational design on atomic level is still a priority. Entropy, as one of the most …

Mechanochemical synthesis of high entropy oxide materials under ambient conditions: dispersion of catalysts via entropy maximization

H Chen, W Lin, Z Zhang, K Jie, DR Mullins… - ACS Materials …, 2019 - ACS Publications
The solid-solution metal oxide (NiMgCuZnCo) O is the first known high-entropy (HE) metal
oxide synthesized, forming a poster child of the emerging high-entropy oxide materials …

Advances in polymerizations modulated by external stimuli

AM Doerr, JM Burroughs, SR Gitter, X Yang… - ACS …, 2020 - ACS Publications
Synthetic polymer chemistry endeavors to imitate the spatial and temporal control exhibited
within biological systems to obtain well-defined polymeric materials with unique structures …