A subsidiary fast-diffusing substitution mechanism of Al in forsterite investigated using diffusion experiments under controlled thermodynamic conditions

I Zhukova, H O'Neill, IH Campbell - Contributions to Mineralogy and …, 2017 - Springer
Diffusion of Al in synthetic forsterite was studied at atmospheric pressure from 1100 to 1500°
C in air along [100] with activities of SiO 2, MgO and Al 2 O 3 (a SiO2, a MgO and a Al2O3) …

Hydrogen diffusion in Ti-doped forsterite and the preservation of metastable point defects

MC Jollands, JA Padrón-Navarta, J Hermann… - American …, 2016 - degruyter.com
The effect of trace concentrations of Ti on the rate and mechanism of hydrogen diffusion in
pure forsterite was investigated experimentally. Forsterite doped with 350–400 ppm Ti …

Explaining the dependence of M-site diffusion in forsterite on silica activity: a density functional theory approach

JMR Muir, M Jollands, F Zhang, AM Walker - Physics and Chemistry of …, 2020 - Springer
Abstract Experimentally, silica activity (aSiO 2) has been shown to have an effect on Mg
diffusion in forsterite, but no fully satisfactory mechanism has yet been proposed. We …

Constraints on aluminum and scandium substitution mechanisms in forsterite, periclase, and larnite: High-resolution NMR

RJ McCarty, JF Stebbins - American Mineralogist, 2017 - degruyter.com
The incorporation of incompatible Al in forsterite is particularly interesting due to its
relevance in Al olivine-spinel geobarometry techniques as well as the proposed influence of …

Mineral–melt partition coefficients and the problem of multiple substitution mechanisms: insights from the rare earths in forsterite and protoenstatite

AD Burnham, HSC O'Neill - Contributions to Mineralogy and Petrology, 2020 - Springer
A trace element may substitute into a mineral by more than one substitution mechanism,
complicating the thermodynamic description of its partition coefficients. In order to …

Calculation of the energetics of water incorporation in majorite garnet

JS Pigott, K Wright, JD Gale, WR Panero - American Mineralogist, 2015 - degruyter.com
Abstract Interpretation of lateral variations in upper mantle seismic wave speeds requires
constraints on the relationship between elasticity and water concentration at high pressure …

Electrophoretic deposition and an investigation of co-dopants effect on luminescence property of Mg2SiO4: Eu3+ phosphors

M Ghahari, AR Naeimi - Journal of Rare Earths, 2017 - Elsevier
Forsterite particles doped with europium ions (Eu 3+) were synthesized via a solution
combustion method. The effect of co-dopants on photoluminescence intensity was …

Lithium defects and diffusivity in forsterite

F Zhang, K Wright - Geochimica et Cosmochimica Acta, 2012 - Elsevier
Lithium is an important geochemical tracer used to infer the thermal and chemical evolution
of minerals in the Earth's upper mantle. Knowledge of point defect chemistry and diffusion is …

[HTML][HTML] Li 同位素在斜顽辉石, 镁铝榴石及镁铝尖晶石晶格内扩散与分馏的理论计算研究

蒋佳俊, 梁光明, 靳佳冀, 张飞武 - 岩石学报, 2018 - html.rhhz.net
斜顽辉石, 镁铝榴石和镁铝尖晶石作为辉石族, 石榴石族以及尖晶石族中的重要端元,
是地球上地幔主要组成矿物. Li 同位素是重要的地幔地球化学示踪剂, 其在橄榄石 …

Modelling of neutral vacancies in forsterite mineral

A Stashans, Y Flores - International Journal of Modern Physics B, 2013 - World Scientific
Density functional theory and generalized gradient approximation have been employed to
study Mg, Si and O vacancies in the Mg 2 SiO 4 forsterite mineral. Microstructure of defect …