Carbenes are important intermediates in organic chemistry and have been widely applied in
various types of organic reactions, ranging from cycloaddition reactions and sigmatropic …

Considering the recent rapid advancement of synthetic technologies promoted by visible
light in the last 15 years, the use of photocatalysts has been rightfully justified based on the …

The development of new sustainable reactions and protocols is essential to fulfill the
growing demands of every branch of organic chemistry for greener synthetic methodologies …

We developed an efficient visible-light-mediated formal carbene insertion reaction of 1, 3-
diketones with diazoesters for the construction of enantioenriched 1, 4-dicarbonyl …

While asymmetric insertion of metal carbenes into H–X (X= C, N, O, etc.) bonds has been
well-established, asymmetric control over free carbenes is challenging due to the presence …

Among the available methods to increase the molecular complexity, sigmatropic
rearrangements occupy a distinct position in organic synthesis. Despite being known for …

In recent years, visible light-induced reactions of diazo compounds have attracted
increasing attention in organic synthesis, leading to improvement of existing reactions, as …

A visible light and base promoted OH insertion/cyclization of para-quinone methides with
aryl diazoacetates is developed. This one-pot two step reaction offers a mild and efficient …

In recent decades, the traceless nature of visible photons has been exploited for the
development of efficient synthetic strategies for the photoconversion of colourless …

A blue-light-emitting diode (LED) promoted coupling of aryl diazoacetates with sulfur ylides
is described. This protocol features mild conditions, good functional group tolerance, and …