Gases like H2, N2, CO2, and CO are increasingly recognized as critical feedstock in “green”
energy conversion and as sources of nitrogen and carbon for the agricultural and chemical …

Bioelectrocatalysis is an interdisciplinary research field combining biocatalysis and
electrocatalysis via the utilization of materials derived from biological systems as catalysts to …

Hydrogenases catalyze the reversible conversion of molecular hydrogen to protons and
electrons via a heterolytic splitting mechanism. The active sites of [NiFe] hydrogenases …

FeFe hydrogenases are the most efficient H2-producing enzymes. However, inactivation by
O2 remains an obstacle that prevents them being used in many biotechnological devices …

Some enzymes, including those that are involved in the activation of small molecules such
as H2 or CO2, can be wired to electrodes and function in either direction of the reaction …

The integration of sensitive catalysts in redox matrices opens up the possibility for their
protection from deactivating molecules such as O2.[FeFe]‐hydrogenases are enzymes …

The observation that some homologous enzymes have the same active site but very different
catalytic properties demonstrates the importance of long-range effects in enzyme catalysis …

Molecular catalysis of H2 production from the electrochemical reduction of acids by
transition-metal complexes is one of the key issues of modern energy challenges. The …

Intensive research during the last 15 years on mechanistic understanding of hydrogenases,
the key enzyme for H2 transformation in many microorganisms, has authorized the concept …

Energy conversion schemes involving dihydrogen hold great potential for meeting
sustainable energy needs, but widespread implementation cannot proceed without solutions …