Photoinduced borylation for the synthesis of organoboron compounds: focus review
YM Tian, XN Guo, H Braunschweig, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …
transformations. The development of practical and convenient ways to synthesize boronate …
(Hetero) arene-fused boroles: a broad spectrum of applications
J He, F Rauch, M Finze, TB Marder - Chemical Science, 2021 - pubs.rsc.org
(Hetero) arene-fused boroles are a class of compounds containing a 5-membered boron
diene-ring. Based on their molecular framework, the (hetero) arene-fused boroles can be …
diene-ring. Based on their molecular framework, the (hetero) arene-fused boroles can be …
Triarylboron‐doped acenethiophenes as organic sonosensitizers for highly efficient sonodynamic therapy with low phototoxicity
The development of efficient organic sonosensitizers is crucial for sonodynamic therapy
(SDT) in the field of cancer treatment. Herein, a new strategy for the development of efficient …
(SDT) in the field of cancer treatment. Herein, a new strategy for the development of efficient …
Thermodynamic equilibrium between locally excited and charge-transfer states through thermally activated charge transfer in 1-(pyren-2′-yl)-o-carborane
L Ji, S Riese, A Schmiedel, M Holzapfel, M Fest… - Chemical …, 2022 - pubs.rsc.org
Reversible conversion between excited-states plays an important role in many
photophysical phenomena. Using 1-(pyren-2′-yl)-o-carborane as a model, we studied the …
photophysical phenomena. Using 1-(pyren-2′-yl)-o-carborane as a model, we studied the …
Electrophilic C–H Borylation of Aza [5] helicenes Leading to Bowl-Shaped Quasi-[7] Circulenes with Switchable Dynamics
X Zhang, F Rauch, J Niedens, RB da Silva… - Journal of the …, 2022 - ACS Publications
The intrinsic relationship between helicenes and circulenes is of fundamental interest and
importance in molecular engineering. Herein, electrophilic borylation of phenanthroline …
importance in molecular engineering. Herein, electrophilic borylation of phenanthroline …
Synthetic Approaches to Triarylboranes from 1885 to 2020
SM Berger, M Ferger, TB Marder - Chemistry–A European …, 2021 - Wiley Online Library
In recent years, research in the fields of optoelectronics, anion sensors and bioimaging
agents have been greatly influenced by novel compounds containing triarylborane motifs …
agents have been greatly influenced by novel compounds containing triarylborane motifs …
Tuning the π-bridge of quadrupolar triarylborane chromophores for one-and two-photon excited fluorescence imaging of lysosomes in live cells
S Griesbeck, E Michail, C Wang, H Ogasawara… - Chemical …, 2019 - pubs.rsc.org
A series of tetracationic quadrupolar chromophores containing three-coordinate boron π-
acceptors linked by different π-bridges, namely 4, 4′-biphenyl, 2, 7-pyrene, 2, 7-fluorene, 3 …
acceptors linked by different π-bridges, namely 4, 4′-biphenyl, 2, 7-pyrene, 2, 7-fluorene, 3 …
Fully conjugated azacorannulene dimer as large diaza [80] fullerene fragment
W Wang, F Hanindita, Y Hamamoto, Y Li… - Nature communications, 2022 - nature.com
A fully conjugated azacorannulene dimer with a large π-surface (76π system) was
successfully synthesized from a fully conjugated bifunctional polycyclic aromatic azomethine …
successfully synthesized from a fully conjugated bifunctional polycyclic aromatic azomethine …
The magic of biaryl linkers: the electronic coupling through them defines the propensity for excited-state symmetry breaking in quadrupolar acceptor–donor–acceptor …
Charge transfer (CT) is key for molecular photonics, governing the optical properties of
chromophores comprising electron-rich and electron-deficient components. In photoexcited …
chromophores comprising electron-rich and electron-deficient components. In photoexcited …
Computationally Guided Molecular Design to Minimize the LE/CT Gap in D‐π‐A Fluorinated Triarylboranes for Efficient TADF via D and π‐Bridge Tuning
AK Narsaria, F Rauch, J Krebs, P Endres… - Advanced Functional …, 2020 - Wiley Online Library
In this combined experimental and theoretical study, a computational protocol is reported to
predict the excited states in D‐π‐A compounds containing the B (FXyl) 2 (FXyl= 2, 6‐bis …
predict the excited states in D‐π‐A compounds containing the B (FXyl) 2 (FXyl= 2, 6‐bis …