Photoinduced borylation for the synthesis of organoboron compounds: focus review

YM Tian, XN Guo, H Braunschweig, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …

(Hetero) arene-fused boroles: a broad spectrum of applications

J He, F Rauch, M Finze, TB Marder - Chemical Science, 2021 - pubs.rsc.org
(Hetero) arene-fused boroles are a class of compounds containing a 5-membered boron
diene-ring. Based on their molecular framework, the (hetero) arene-fused boroles can be …

Triarylboron‐doped acenethiophenes as organic sonosensitizers for highly efficient sonodynamic therapy with low phototoxicity

K Liu, Z Jiang, F Zhao, W Wang, F Jäkle… - Advanced …, 2022 - Wiley Online Library
The development of efficient organic sonosensitizers is crucial for sonodynamic therapy
(SDT) in the field of cancer treatment. Herein, a new strategy for the development of efficient …

Thermodynamic equilibrium between locally excited and charge-transfer states through thermally activated charge transfer in 1-(pyren-2′-yl)-o-carborane

L Ji, S Riese, A Schmiedel, M Holzapfel, M Fest… - Chemical …, 2022 - pubs.rsc.org
Reversible conversion between excited-states plays an important role in many
photophysical phenomena. Using 1-(pyren-2′-yl)-o-carborane as a model, we studied the …

Electrophilic C–H Borylation of Aza [5] helicenes Leading to Bowl-Shaped Quasi-[7] Circulenes with Switchable Dynamics

X Zhang, F Rauch, J Niedens, RB da Silva… - Journal of the …, 2022 - ACS Publications
The intrinsic relationship between helicenes and circulenes is of fundamental interest and
importance in molecular engineering. Herein, electrophilic borylation of phenanthroline …

Synthetic Approaches to Triarylboranes from 1885 to 2020

SM Berger, M Ferger, TB Marder - Chemistry–A European …, 2021 - Wiley Online Library
In recent years, research in the fields of optoelectronics, anion sensors and bioimaging
agents have been greatly influenced by novel compounds containing triarylborane motifs …

Tuning the π-bridge of quadrupolar triarylborane chromophores for one-and two-photon excited fluorescence imaging of lysosomes in live cells

S Griesbeck, E Michail, C Wang, H Ogasawara… - Chemical …, 2019 - pubs.rsc.org
A series of tetracationic quadrupolar chromophores containing three-coordinate boron π-
acceptors linked by different π-bridges, namely 4, 4′-biphenyl, 2, 7-pyrene, 2, 7-fluorene, 3 …

Fully conjugated azacorannulene dimer as large diaza [80] fullerene fragment

W Wang, F Hanindita, Y Hamamoto, Y Li… - Nature communications, 2022 - nature.com
A fully conjugated azacorannulene dimer with a large π-surface (76π system) was
successfully synthesized from a fully conjugated bifunctional polycyclic aromatic azomethine …

The magic of biaryl linkers: the electronic coupling through them defines the propensity for excited-state symmetry breaking in quadrupolar acceptor–donor–acceptor …

JA Clark, D Kusy, O Vakuliuk, M Krzeszewski… - Chemical …, 2023 - pubs.rsc.org
Charge transfer (CT) is key for molecular photonics, governing the optical properties of
chromophores comprising electron-rich and electron-deficient components. In photoexcited …

Computationally Guided Molecular Design to Minimize the LE/CT Gap in D‐π‐A Fluorinated Triarylboranes for Efficient TADF via D and π‐Bridge Tuning

AK Narsaria, F Rauch, J Krebs, P Endres… - Advanced Functional …, 2020 - Wiley Online Library
In this combined experimental and theoretical study, a computational protocol is reported to
predict the excited states in D‐π‐A compounds containing the B (FXyl) 2 (FXyl= 2, 6‐bis …