Hypervalent aryliodoumiums are intensively investigated as arylating agents. They are
excellent surrogates to aryl halides, and moreover they exhibit better reactivity, which allows …

The story of C− C bond formation includes several reactions, and surely Suzuki‐Miyaura is
among the most outstanding ones. Herein, a brief historical overview of insights regarding …

Although Suzuki–Miyaura cross-coupling is one of the most convenient and well-developed
cross-coupling reactions, its applications to the asymmetric version to deliver highly …

The stereocontrolled construction of C− C bonds remains one of the foremost challenges in
organic synthesis. At the heart of any chemical synthesis of a natural product or designed …

Catalytic dynamic kinetic asymmetric transformation (DyKAT) provides a powerful tool to
access chiral stereoisomers from racemic substrates. Such transformation has been widely …

In the transition-metal-catalyzed cross-coupling reactions, the use of the first row transition
metals as catalysts is much more appealing than the precious metals owing to the apparent …

Axially chiral biaryl scaffolds are essential structural units in chemistry. The asymmetric Pd-
catalyzed Suzuki–Miyaura cross-coupling reaction has been widely recognized as one of …

Axial chirality is a key feature of many important organic molecules, such as biologically
active compounds, stereogenic ligands and optically pure materials. Significant efforts in the …

A scalable enantioselective nickel-catalyzed electrochemical reductive homocoupling of aryl
bromides has been developed, affording enantioenriched axially chiral biaryls in good yield …

Atroposelective synthesis of axially chiral biaryls by palladium‐catalyzed C− H olefination,
using tert‐leucine as an inexpensive, catalytic, and transient chiral auxiliary, has been …