Manganese-catalyzed hydrogenation, dehydrogenation, and hydroelementation reactions

K Das, S Waiba, A Jana, B Maji - Chemical Society Reviews, 2022 - pubs.rsc.org
The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …

Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes

ES Gulyaeva, ES Osipova, R Buhaibeh… - Coordination Chemistry …, 2022 - Elsevier
Rapidly emerging application of organometallic manganese complexes incorporating less
elaborated mono-and bidentate donor ligands in catalytic hydrogenation, transfer …

Well-defined phosphine-free manganese (II)-complex-catalyzed synthesis of quinolines, pyrroles, and pyridines

A Maji, S Gupta, M Maji, S Kundu - The Journal of Organic …, 2022 - ACS Publications
Herein, we report a simple, phosphine-free, and inexpensive catalytic system based on a
manganese (II) complex for synthesizing different important N-heterocycles such as …

Guerbet-type β-alkylation of secondary alcohols catalyzed by chromium chloride and its corresponding NNN pincer complex

H Narjinari, N Tanwar, L Kathuria, RV Jasra… - Catalysis Science & …, 2022 - pubs.rsc.org
The β-alkylation of secondary alcohols has been successfully accomplished using earth
abundant, inexpensive and environmentally benign 3d transition metal chromium salt CrCl3 …

Manganese-catalyzed reformation of vicinal glycols to α-hydroxy carboxylic acids with the liberation of hydrogen gas

S Waiba, M Maiti, B Maji - ACS Catalysis, 2022 - ACS Publications
Conversion of readily available feedstocks to valuable platform chemicals via an eco-
friendly catalytic pathway has always been one of the key focuses of synthetic chemists. In …

Alcohols as Substrates in Transition-Metal-Catalyzed Arylation, Alkylation, and Related Reactions

A Cook, SG Newman - Chemical Reviews, 2024 - ACS Publications
Alcohols are abundant and attractive feedstock molecules for organic synthesis. Many
methods for their functionalization require them to first be converted into a more activated …

NNN Pincer-Manganese-Catalyzed Guerbet-Type β-Alkylation of Alcohols under Microwave Irradiation

A Bisarya, RV Jasra, A Kumar - Organometallics, 2023 - ACS Publications
A series of manganese carbonyl complexes based on bis (imino) pyridine ligands of the type
R2NNN (R= Cy, i Pr, Ph, p-FC6H4) were synthesized. While the complex appears to be an …

Sustainable Synthesis of α‐Hydroxycarboxylic Acids by Manganese Catalyzed Acceptorless Dehydrogenative Coupling of Ethylene Glycol and Primary Alcohols

S Waiba, K Maji, M Maiti, B Maji - Angewandte Chemie, 2023 - Wiley Online Library
Herein, we report a straightforward synthesis of valuable α‐hydroxycarboxylic acid
molecules via an acceptorless dehydrogenative coupling of ethylene glycol and primary …

Recent advances in C/N-alkylation with alcohols through hydride transfer strategies

M Jafarzadeh, SH Sobhani, K Gajewski… - Organic & Biomolecular …, 2022 - pubs.rsc.org
This review highlights the most recent reports in three powerful and ever-growing fields of
borrowing hydrogen, acceptorless dehydrogenative coupling, and base-mediated hydride …

Unlocking the potential of metal ligand cooperation for enantioselective transformations

TF Ramspoth, J Kootstra… - Chemical Society Reviews, 2024 - pubs.rsc.org
Metal–ligand cooperation, in which both the metal and the ligand of a transition metal
complex actively participate in chemical transformations leading to enhanced reactivity or …