Manganese-catalyzed hydrogenation, dehydrogenation, and hydroelementation reactions
The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …
abundant transition metals due to their ready availability, economic advantage, and novel …
Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes
ES Gulyaeva, ES Osipova, R Buhaibeh… - Coordination Chemistry …, 2022 - Elsevier
Rapidly emerging application of organometallic manganese complexes incorporating less
elaborated mono-and bidentate donor ligands in catalytic hydrogenation, transfer …
elaborated mono-and bidentate donor ligands in catalytic hydrogenation, transfer …
Well-defined phosphine-free manganese (II)-complex-catalyzed synthesis of quinolines, pyrroles, and pyridines
Herein, we report a simple, phosphine-free, and inexpensive catalytic system based on a
manganese (II) complex for synthesizing different important N-heterocycles such as …
manganese (II) complex for synthesizing different important N-heterocycles such as …
Guerbet-type β-alkylation of secondary alcohols catalyzed by chromium chloride and its corresponding NNN pincer complex
The β-alkylation of secondary alcohols has been successfully accomplished using earth
abundant, inexpensive and environmentally benign 3d transition metal chromium salt CrCl3 …
abundant, inexpensive and environmentally benign 3d transition metal chromium salt CrCl3 …
Manganese-catalyzed reformation of vicinal glycols to α-hydroxy carboxylic acids with the liberation of hydrogen gas
Conversion of readily available feedstocks to valuable platform chemicals via an eco-
friendly catalytic pathway has always been one of the key focuses of synthetic chemists. In …
friendly catalytic pathway has always been one of the key focuses of synthetic chemists. In …
Alcohols as Substrates in Transition-Metal-Catalyzed Arylation, Alkylation, and Related Reactions
Alcohols are abundant and attractive feedstock molecules for organic synthesis. Many
methods for their functionalization require them to first be converted into a more activated …
methods for their functionalization require them to first be converted into a more activated …
NNN Pincer-Manganese-Catalyzed Guerbet-Type β-Alkylation of Alcohols under Microwave Irradiation
A series of manganese carbonyl complexes based on bis (imino) pyridine ligands of the type
R2NNN (R= Cy, i Pr, Ph, p-FC6H4) were synthesized. While the complex appears to be an …
R2NNN (R= Cy, i Pr, Ph, p-FC6H4) were synthesized. While the complex appears to be an …
Sustainable Synthesis of α‐Hydroxycarboxylic Acids by Manganese Catalyzed Acceptorless Dehydrogenative Coupling of Ethylene Glycol and Primary Alcohols
Herein, we report a straightforward synthesis of valuable α‐hydroxycarboxylic acid
molecules via an acceptorless dehydrogenative coupling of ethylene glycol and primary …
molecules via an acceptorless dehydrogenative coupling of ethylene glycol and primary …
Recent advances in C/N-alkylation with alcohols through hydride transfer strategies
M Jafarzadeh, SH Sobhani, K Gajewski… - Organic & Biomolecular …, 2022 - pubs.rsc.org
This review highlights the most recent reports in three powerful and ever-growing fields of
borrowing hydrogen, acceptorless dehydrogenative coupling, and base-mediated hydride …
borrowing hydrogen, acceptorless dehydrogenative coupling, and base-mediated hydride …
Unlocking the potential of metal ligand cooperation for enantioselective transformations
TF Ramspoth, J Kootstra… - Chemical Society Reviews, 2024 - pubs.rsc.org
Metal–ligand cooperation, in which both the metal and the ligand of a transition metal
complex actively participate in chemical transformations leading to enhanced reactivity or …
complex actively participate in chemical transformations leading to enhanced reactivity or …