Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …

Direct difunctionalization of simple alkenes, the incorporation of two functional groups onto a
carbon–carbon double bond, is of particular interest to the chemical community owing to its …

Catalytic alkene difunctionalization via Si− H and C− H activations represents an ideal atom‐
and step‐economic pathway for quick assembly of molecular complexity. We herein …

The selective radical/radical cross‐coupling of two different organic radicals is a great
challenge due to the inherent activity of radicals. In this paper, a copper‐catalyzed …

An unprecedented and challenging radical–radical cross‐coupling of α‐aminoalkyl radicals
with monofluoroalkenyl radicals derived from gem‐difluoroalkenes was achieved. This first …

N‐Alkenoxypyridinium salts have been used as synthons for the umpolung reaction of
enolates for the preparation of α‐functionalized carbonyl compounds. In contrast, we found …

Direct radical additions to terminal alkynes have been widely employed in organic synthesis,
providing credible access to the anti‐Markovnikov products. Because of the Kharasch effect …

A controllable mono‐and di‐multifluoroarylation of acyclic and cyclic N‐aryl amines with aryl
fluorides by photocatalyzed dual C (sp3)− H/C (sp2)− F functionalization has been …

Abstract Radikal‐Radikal‐Kupplungen sind nahezu diffusionskontrollierte Prozesse. Daher
sind selektive Kreuzkupplungen zweier unterschiedlicher Radikale schwierig zu realisieren …

Fluorinated ketones are intriguing compounds in synthetic chemistry and life science‐
related fields. The development of efficient methodologies to obtain these compounds is of …