Why is ferrocene so exceptional?

D Astruc - European Journal of Inorganic Chemistry, 2017 - Wiley Online Library
The appearance of ferrocene in the middle of the 20th century has revolutionized
organometallic chemistry and is now providing applications in areas as varied and …

Synthetic routes to N-heterocyclic carbene precursors

L Benhamou, E Chardon, G Lavigne… - Chemical …, 2011 - ACS Publications
N-Heterocyclic carbenes (NHCs) are defined as singlet carbenes, in which the divalent
carbenic center is connected directly to at least one nitrogen atom within the heterocycle. 1 …

Synthesis of planar chiral ferrocenes via enantioselective remote C–H activation

L Zhou, HG Cheng, L Li, K Wu, J Hou, C Jiao… - Nature Chemistry, 2023 - nature.com
Planar chiral ferrocenes are widely studied structures in asymmetric catalysis, materials
science and medicinal chemistry. Although synthetic methods for 1, 2-disubstituted planar …

Reactions of the 21st century: two decades of innovative catalyst design for palladium-catalyzed cross-couplings

PG Gildner, TJ Colacot - Organometallics, 2015 - ACS Publications
A brief account of the major developments of palladium-catalyzed cross-coupling during the
last two decades is highlighted chronologically, with an emphasis on the personal …

Biaryl synthesis with arenediazonium salts: cross-coupling, CH-arylation and annulation reactions

FX Felpin, S Sengupta - Chemical Society Reviews, 2019 - pubs.rsc.org
The rich legacy of arenediazonium salts in the synthesis of unsymmetrical biaryls, built
around the seminal works of Pschorr, Gomberg and Bachmann more than a century ago …

Bioorganometallic chemistry of ferrocene

DR Van Staveren, N Metzler-Nolte - Chemical reviews, 2004 - ACS Publications
In 1951, a new compound containing iron and two cyclopentadienide ligands was reported.
1, 2 Although even the first reports noted its high and unexpected stability, the correct …

A new age for iron: antitumoral ferrocenes

SS Braga, AMS Silva - Organometallics, 2013 - ACS Publications
From the core of the earth to the core of the archetypal organometallic compound ferrocene,
iron and its compounds contribute to create many aspects of our reality: the earth's …

[图书][B] Chiral ferrocenes in asymmetric catalysis: synthesis and applications

LX Dai, XL Hou - 2010 - books.google.com
This book meets the long-felt need for a reference on ferrocenes with the focus on catalysis.
It provides a thorough overview of the synthesis and characterization of different types of …

Recent advances in the synthesis, biological activities and various applications of ferrocene derivatives

FA Larik, A Saeed, TA Fattah… - Applied …, 2017 - Wiley Online Library
Ferrocene derivatives constitute an important class of organometallic compounds with not
only an extensive range of biological activities but also diverse industrial as well as material …

Selective syntheses of planar-chiral ferrocenes

D Schaarschmidt, H Lang - Organometallics, 2013 - ACS Publications
Planar-chiral ferrocenes are widely applied in catalytic asymmetric transformations in
scientific research as well as in industry. A plethora of different methodologies have been …