A decade update on solvent and catalyst-free neat organic reactions: a step forward towards sustainability
Particular success has been achieved in the synthesis of new products and in processes
since the twelve principles of “green chemistry” were formulated in the 1990s. These …
since the twelve principles of “green chemistry” were formulated in the 1990s. These …
Catalyst-free and solvent-free hydroboration of aldehydes
H Stachowiak, J Kaźmierczak, K Kuciński… - Green …, 2018 - pubs.rsc.org
A simple catalyst-free and solvent-free method for the hydroboration of various aldehydes
bearing a wide array of electron-withdrawing and electron-donating groups was developed …
bearing a wide array of electron-withdrawing and electron-donating groups was developed …
Double reversible networks: improvement of self-healing in hybrid materials via combination of diels–alder cross-linking and hydrogen bonds
S Schäfer, G Kickelbick - Macromolecules, 2018 - ACS Publications
Intrinsic self-healing materials rely on a reversible bond formation after failure. In this study
we report hybrid materials that contain two intrinsic self-healing forces: The reversible …
we report hybrid materials that contain two intrinsic self-healing forces: The reversible …
Acetonitrile and benzonitrile as versatile amino sources in copper-catalyzed mild electrochemical C–H amidation reactions
S Strekalova, A Kononov, I Rizvanov, Y Budnikova - RSC advances, 2021 - pubs.rsc.org
A mild, efficient electrochemical approach to the site-selective direct C–H amidation of
benzene and its derivatives with acetonitrile and benzonitrile has been developed. It has …
benzene and its derivatives with acetonitrile and benzonitrile has been developed. It has …
Recent advances in chemoselective acylation of amines
F Piazzolla, A Temperini - Tetrahedron Letters, 2018 - Elsevier
N-chemoselective acylation of amines in the presence of competing nucleophiles, like
alcohols and thiols, is by no means a simple achievement in organic synthesis and even …
alcohols and thiols, is by no means a simple achievement in organic synthesis and even …
General, mild, and metal-free synthesis of phenyl selenoesters from anhydrides and their use in peptide synthesis
A Temperini, F Piazzolla, L Minuti… - The Journal of …, 2017 - ACS Publications
A mild, practical, and simple procedure for phenyl selenoesters synthesis from several
anhydrides and diphenyl diselenide was developed. This transition-metal-free method …
anhydrides and diphenyl diselenide was developed. This transition-metal-free method …
Thioacids mediated selective and mild N-acylation of amines
N-Acylated amines are ubiquitous in nature. Selective N-acylation at neutral conditions
remains a key area of interest. Here we are reporting the copper sulfate-mediated highly …
remains a key area of interest. Here we are reporting the copper sulfate-mediated highly …
Tropylium‐BF4 as Organocatalyst for Microwave‐assisted Beckmann rearrangement in [TMG][BF4]: One‐pot conversion of Ketones to Amides
A Anchi, RG Kalkhambkar, SM Sutar, RS Naik… - …, 2023 - Wiley Online Library
The microwave assisted one pot efficient conversion of ketones into respective amides has
been achieved by utilization of environmentally benign catalytic system tailored by tropylium …
been achieved by utilization of environmentally benign catalytic system tailored by tropylium …
Observations concerning the synthesis of tryptamine homologues and branched tryptamine derivatives via the borrowing hydrogen process: synthesis of psilocin …
Observations concerning the synthesis of substituted tryptamine derivatives starting from
indoles and 1, n-amino alcohols via the borrowing hydrogen process are discussed. This …
indoles and 1, n-amino alcohols via the borrowing hydrogen process are discussed. This …
Carbon dioxide as a reversible amine-protecting agent in selective Michael additions and acylations
A Peeters, R Ameloot, DE De Vos - Green chemistry, 2013 - pubs.rsc.org
Carbon dioxide can be used as a temporary protecting group for amines. A carbamic acid is
formed reversibly when CO2 is bubbled through a solution of a sufficiently basic primary …
formed reversibly when CO2 is bubbled through a solution of a sufficiently basic primary …