The asymmetric synthesis of aziridines

HMI Osborn, J Sweeney - Tetrahedron: Asymmetry, 1997 - Elsevier
The ability of aziridines to undergo highly regio-and stereoselective ring-opening reactions
renders them of great value in organic synthesis. l This ability has not gone unnoticed in …

Die chemie vicinaler diamine

D Lucet, T Le Gall, C Mioskowski - Angewandte Chemie, 1998 - Wiley Online Library
Vor allem bei enantioselektiven Synthesen werden vicinale Diamine (1, 2‐Diamine) 1 und
Verbindungen, die auf einfachem Weg aus diesen erhalten werden können–wie 1, 2 …

[PDF][PDF] Highlights of the chemistry of enantiomerically pure aziridine-2-carboxylates

WK Lee, HJ Ha - Aldrichimica Acta, 2003 - bioorg.org
Acta33#3 squeeze Page 1 VOL.36, NO.2 • 2003 CHEMISTSHELPINGCHEMIS TS SPECIAL
FOCUS ON NONRACEMIC AZIRIDINES AND OXAZOLINES Aziridines and Oxazolines …

A Thermodynamic Preference of Chiral N-Methanesulfonyl and N-Arenesulfonyl 2,3-cis-3-Alkyl-2-Vinylaziridines over Their 2,3-Trans-Isomers:  Useful Palladium(0) …

T Ibuka, N Mimura, H Aoyama, M Akaji… - The Journal of …, 1997 - ACS Publications
Palladium (0)-catalyzed reactions of N-methanesulfonyl-or N-(arenesulfonyl)-3-alkyl-2-
vinylaziridines reveal that 2, 3-cis-isomers are more stable than the corresponding 2, 3-trans …

Conformationally rigid cyclic α-amino acids in the design of peptidomimetics, peptide models and biologically active compounds

IV Komarov, AO Grigorenko, AV Turov… - Russian chemical …, 2004 - pubs.rsc.org
A class of conformationally rigid cyclic α-amino acids that can be used in the synthesis of
peptidomimetics, peptide models and biologically active compounds is surveyed. The rigid …

A convenient method for the synthesis of 2-arylaziridines from styrene derivatives via 2-arylethenyl (diphenyl) sulfonium salts

J Matsuo, H Yamanaka, A Kawana… - Chemistry …, 2003 - academic.oup.com
Styrene derivatives reacted with diphenyl (trifluoromethanesulfonyloxy) sulfonium
trifluoromethanesulfonate (1) at low temperature to afford 2-arylethenyl (diphenyl) sulfonium …

Amines and amides

M North - Contemporary organic synthesis, 1997 - pubs.rsc.org
This review covers the literature published during 1996. References were obtained in the
same way as in previous years, and the review has the same format as that used last …

[PDF][PDF] Aziridine-2-carboxylates: preparation, nucleophilic ring opening, and ring expansion

T Ishikawa - Heterocycles, 2012 - triggered.stanford.clockss.org
AZIRIDINE-2-CARBOXYLATES: PREPARATION, NUCLEOPHILIC RING OPENING, AND RING
EXPANSION Tsutomu Ishikawa* Graduate School of Pharma Page 1 HETEROCYCLES, Vol. 85 …

Two-Step Asymmetric Synthesis of Disubstituted N-Tosyl Aziridines Having 98−100% ee:  Use of a Phosphazene Base

A Solladié-Cavallo, M Roje, R Welter… - The Journal of Organic …, 2004 - ACS Publications
Unknown diaryl (1− 3) and alkyl-phenyl (4, 5) N-tosyl aziridines have been successfully
synthesized from pure (R, R, R, SS)-(−)-sulfonium salt derived from Eliel's oxathiane …

Synthesis of aziridines

JB Sweeney - Aziridines and Epoxides in Organic Synthesis, 2006 - Wiley Online Library
In 1999, Bob Atkinson wrote [1] that aziridination reactions were “< qs> epoxidation's poor
relation< qe>”, and this was undoubtedly true at that time: the scope of the synthetic methods …