The nitrile group is an important functional group widely found in both pharmaceutical
agents and natural products. More than 30 nitrile-containing pharmaceuticals have been …

We previously reviewed the use of 19 F NMR in the broad field of chemical biology [Cobb,
SL; Murphy, CD J. Fluorine Chem. 2009, 130, 132–140] and present here a summary of the …

Abstract Pentafluorosulfanyl (SF5)‐containing compounds and corresponding analogs are a
highly valuable class of fluorine‐containing building blocks owing to their unique properties …

This short review covers the most important advances published in the literature during the
last five years, concerning the synthesis, chemical modifications, and applications of SF 5 …

We describe a synthetic approach to sterically hindered α-hydroxy carbonyl compounds
through radical–radical coupling. An organic photoredox catalysis reaction converts an …

The photoactivation of notoriously inert sulfur hexafluoride represents a challenge for
photochemistry. This short review summarizes recently published efforts and the …

With the goal of accessing yet unknown SF5-cyclopropyl building blocks, the radical addition
of SF5Cl to cyclopropenes was investigated. Addition of the SF5 radical occurs …

A new method for the addition of SF 5 Cl on unsaturated compounds was developed, based
on the use of an electron donor-acceptor (EDA)-complex and visible light irradiation. The …

Recently, we suggested liquid and high‐boiling TIPS‐CC‐SF5 (TASP) as a versatile reagent
to access so far elusive SF5‐containing building blocks by less specialized laboratories …

In organic synthesis, incorporating two functional groups into the carbon‐carbon double
bond of α, β‐unsaturated amides is challenging due to the electron‐deficient nature of the …