This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …

Fluorinated organic compounds increasingly gain importance in numerous areas of
chemistry and everyday life. Building blocks which contain fluorinated entities are of high …

Herein, we report a hydrodefluorination reaction of polyfluoroarenes catalyzed by
bismuthinidenes, Phebox-Bi (I) and OMe-Phebox-Bi (I). Mechanistic studies on the …

The activation and functionalization of carbon–fluorine bonds can be considered as a major
challenge in organometallic chemistry. The growing demand for means to introduce fluorine …

C–F bond activation is currently considered to be “a hot topic” in many different but
interconnected fields of research, due to its inherent inertness and unique properties. While …

With fluoroaromatic compounds increasingly employed as scaffolds in agrochemicals and
active pharmaceutical ingredients, the development of methods which facilitate …

In the last two decades, tremendous progress has been made towards the development of
compounds with s-and p-block elements. β-Diketiminate ligands have been widely used in …

The direct employment of polyfluoroarenes and gem-difluoroalkenes as building blocks is
regarded as one of the most effective and straightforward strategies for the introduction of …

This perspective article focuses its attention on the most recent advances in
hydrodefluorination processes catalyzed by late transition metal complexes, a field that has …

Abstract The nickel‐mediated [3+ 2] cycloaddition of 2‐trifluoromethyl‐1‐alkenes with
alkynes afforded fluorine‐containing multi‐substituted cyclopentadienes in a regioselective …