Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …
recommended as reversible deactivation radical polymerization) is undoubtedly a …
Toward green atom transfer radical polymerization: current status and future challenges
Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …
Externally controlled atom transfer radical polymerization
Spatial and temporal regulations of ATRP by external stimuli are presented. Various ATRP
techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current …
techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current …
Macromolecular engineering by atom transfer radical polymerization
K Matyjaszewski, NV Tsarevsky - Journal of the American …, 2014 - ACS Publications
This Perspective presents recent advances in macromolecular engineering enabled by
ATRP. They include the fundamental mechanistic and synthetic features of ATRP with …
ATRP. They include the fundamental mechanistic and synthetic features of ATRP with …
Synthetic approaches for multiblock copolymers
Multiblock copolymers (MBCs) are an emerging class of synthetic polymers that exhibit
different macromolecular architectures and behaviours to those of homopolymers or …
different macromolecular architectures and behaviours to those of homopolymers or …
From non-conventional ideas to multifunctional solvents inspired by green chemistry: fancy or sustainable macromolecular chemistry?
The need for designing a more green approach to reversible-deactivation radical
polymerization (RDRP) results in rapid evolution, enabling its facile scaling up and moving …
polymerization (RDRP) results in rapid evolution, enabling its facile scaling up and moving …
Replacing organics with water: Macromolecular engineering of non-water miscible poly (meth) acrylates via interfacial and ion-pair catalysis SARA ATRP in …
The paper presents the possibility to synthesize immiscible with water, well-defined poly
(meth) acrylates via supplemental activation and reducing agent atom transfer radical …
(meth) acrylates via supplemental activation and reducing agent atom transfer radical …
Tuning the molecular weight distribution from atom transfer radical polymerization using deep reinforcement learning
We devise a novel technique to control the shape of polymer molecular weight distributions
(MWDs) in atom transfer radical polymerization (ATRP). This technique makes use of recent …
(MWDs) in atom transfer radical polymerization (ATRP). This technique makes use of recent …
Poly (vinyl chloride): current status and future perspectives via reversible deactivation radical polymerization methods
CMR Abreu, AC Fonseca, NMP Rocha… - Progress in Polymer …, 2018 - Elsevier
Abstract Poly (vinyl chloride)(PVC) is one of the more consumed polymers worldwide due to
its general versatility and low cost. It is currently used in various applications ranging from …
its general versatility and low cost. It is currently used in various applications ranging from …
Understanding the relationship between catalytic activity and termination in photoATRP: Synthesis of linear and bottlebrush polyacrylates
Linear and bottlebrush polyacrylates were prepared by photomediated atom transfer radical
polymerization (photoATRP) catalyzed by either CuBr2/TPMA (tris (2-pyridylmethyl) amine) …
polymerization (photoATRP) catalyzed by either CuBr2/TPMA (tris (2-pyridylmethyl) amine) …