Radicals derived from Lewis acid/base pairs

LL Liu, DW Stephan - Chemical Society Reviews, 2019 - pubs.rsc.org
While conventional approaches to stabilizing main group radicals have involved the use of
Lewis acids or bases, this tutorial review focuses on new avenues to main group radicals …

Redox-active phenanthrenequinone triangles in aqueous rechargeable zinc batteries

KW Nam, H Kim, Y Beldjoudi, T Kwon… - Journal of the …, 2020 - ACS Publications
Aqueous rechargeable zinc batteries (ZBs) have received considerable attention recently for
large-scale energy storage systems in terms of rate performance, cost, and safety …

Homolytic cleavage of peroxide bonds via a single electron transfer of a frustrated Lewis pair

LL Liu, LL Cao, D Zhu, J Zhou… - Chemical …, 2018 - pubs.rsc.org
Single electron transfer (SET) reactions are effected by the combination of a Mes3P/B
(C6F5) 3 frustrated Lewis pair with benzoyl peroxide derivatives. The resulting homolytic …

Complexes of Metal Halides with Unreduced o-(Imino)quinones

IV Ershova, IN Meshcheryakova, OY Trofimova… - Inorganic …, 2021 - ACS Publications
A series of complexes of metal halides with unreduced quinone-type ligands have been
synthesized and characterized in detail. The 3, 6-di-tert-butyl-o-benzoquinone (1) and 4, 6-di …

The special role of B (C 6 F 5) 3 in the single electron reduction of quinones by radicals

X Tao, CG Daniliuc, R Knitsch, MR Hansen… - Chemical …, 2018 - pubs.rsc.org
In the presence of two molar equiv. of B (C6F5) 3p-benzoquinone reacts with persistent
radicals TEMPO, trityl or decamethylferrocene by single electron transfer to give doubly O …

Isolable Anionic, Neutral and Cationic Radicals from Reactions of N,N′‐Dimesityldiamidocarbene and Lewis Acids

RJ Andrews, DW Stephan - Chemistry–A European Journal, 2020 - Wiley Online Library
Abstract B (C6F5) 3 undergoes nucleophilic attack by N, N′‐dimesityldiamidocarbene
(DAC) with fluoride transfer to the boron center, resulting in a new zwitterion (1). This B− F …

Lewis acid–base pair doping of p-type organic semiconductors

KA Peterson, ML Chabinyc - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
Doping is required to increase the electrical conductivity of organic semiconductors for uses
in electronic and energy conversion devices. The limited number of commonly used p-type …

Isolable Cu(I) Complexes of Extremely Electron-Poor, Completely Unreduced o-Quinone and “Di-o-Quinone” Ligands Stabilized through π–π Interactions in the …

U Albold, C Hoyer, NI Neuman, S Sobottka… - Inorganic …, 2019 - ACS Publications
The copper–quinone interaction plays important roles in diverse fields such as biochemistry,
catalysis, and optically/magnetically switchable materials. Despite this fact, the isolation and …

Structural diversity of 9, 10-phenanthrenequinone molecular complexes with metal halides

IV Ershova, IN Meshcheryakova, OY Trofimova… - Inorganica Chimica …, 2022 - Elsevier
A series of metal halide complexes with 9, 10-phenanthrenequinone (PQ) have been
synthesized and characterized in detail. An interaction of PQ with metal halides leads to …

Donor–acceptor bridge 2, 5-bis (2-oxido-phenyl) thiazolo-[5, 4-d] thiazole derived diruthenium and diosmium systems. Structural and competitive electronic events as …

S Dhara, S Chakraborty, L Seikh, GK Lahiri - Dalton Transactions, 2023 - pubs.rsc.org
The article deals with the structural and electronic forms of hitherto unexplored L2−(H2L= 2,
5-bis (2-hydroxyphenyl) thiazolo-[5, 4-d] thiazole) bridged analogous diruthenium …