Polyolefin Catalyst Research: A Product‐Driven Industrial Perspective

M Atiqullah, HS Al‐Asiri - The Chemical Record, 2022 - Wiley Online Library
This account narrates polyolefin catalyst research at the Research Institute Interdisciplinary
Research Center for Refining & Advanced Chemicals (IRCRAC). We particularly address …

Reaction engineering of polyolefins: the role of catalyst supports in ethylene polymerization on metallocene catalysts

M Ahsan Bashir, TFL McKenna - Polymer Reaction Engineering of …, 2018 - Springer
This chapter presents a brief look at different methods for the polymerization of ethylene
using supported metallocene catalysts, then focuses on the effects that the properties of …

Site-averaged kinetics for catalysts on amorphous supports: an importance learning algorithm

CA Vandervelden, SA Khan, SL Scott… - Reaction Chemistry & …, 2020 - pubs.rsc.org
Ab initio calculations have greatly advanced our understanding of homogeneous catalysts
and crystalline heterogeneous catalysts. In contrast, amorphous heterogeneous catalysts …

Silica/MAO/(n-BuCp) 2 ZrCl 2 catalyst: effect of support dehydroxylation temperature on the grafting of MAO and ethylene polymerization

MA Bashir, T Vancompernolle, RM Gauvin… - Catalysis Science & …, 2016 - pubs.rsc.org
The current study aims to explore the link between the role of silica dehydroxylation
temperature and the catalytic performance of an (n-BuCp) 2ZrCl2 metallocene precursor …

Grafting metal complexes onto amorphous supports: from elementary steps to catalyst site populations via kernel regression

SA Khan, CA Vandervelden, SL Scott… - Reaction Chemistry & …, 2020 - pubs.rsc.org
Ab initio computational studies have made tremendous progress in describing the behavior
of molecular (homogeneous) catalysts and crystalline versions of heterogeneous catalysts …

Ethylene polymerization over novel organic magnesium based V/Ti bimetallic Ziegler-Natta Catalysts

Y Zhou, R Zhang, H Ren, X He, B Liu, N Zhao… - Journal of Organometallic …, 2020 - Elsevier
A series of novel V/Ti bimetallic polyethylene catalysts were developed successfully through
the introduction of vanadium species into the (SiO 2/MgR 2/MgCl 2)· TiCl x Ziegler-Natta …

Silica‐supported (nBuCp)2ZrCl2: effect of catalyst active center distribution on ethylene–1‐hexene copolymerization

M Atiqullah, S Anantawaraskul… - Polymer …, 2014 - Wiley Online Library
Metallocenes are a modern innovation in polyolefin catalysis research. Therefore, two
supported metallocene catalysts—silica/MAO/(nBuCp) 2ZrCl2 (Catalyst 1) and …

Cyclic molecular designed dispersion (CMDD) of Fe2O3 on CeO2 promoted by Au for preferential CO oxidation in hydrogen

A Tavakoli, N Nasiri, Y Mortazavi… - International Journal of …, 2020 - Elsevier
A novel cyclic molecular designed dispersion (CMDD) method was employed to uniformly
deposit 0.0–6.5 wt% Fe on CeO 2. The gold catalysts (0.0–3.8 wt%) supported on Fe 2 O 3 …

Effects of a vanadium post-metallocene catalyst-induced polymer backbone inhomogeneity on UV oxidative degradation of the resulting polyethylene film

M Atiqullah, MS Winston, JE Bercaw, I Hussain… - … degradation and stability, 2012 - Elsevier
A Group 5 post-metallocene precatalyst,(ONO) VCl (THF) 2 (ONO= a bis (phenolate)
pyridine LX2 pincer ligand), activated with modified methylaluminoxane (MMAO-3A) …

Influence of MIL-53 on the catalytic performance of metallocene in propylene polymerization

JS Lee, C Manianglung, HI Jeon, YS Ko - Molecular Catalysis, 2025 - Elsevier
In this study, we investigate the application of metal-organic frameworks (MOFs) as a
support for metallocene catalysts in the polymerization of propylene. MOFs such as MIL-53 …