Polyolefin Catalyst Research: A Product‐Driven Industrial Perspective
M Atiqullah, HS Al‐Asiri - The Chemical Record, 2022 - Wiley Online Library
This account narrates polyolefin catalyst research at the Research Institute Interdisciplinary
Research Center for Refining & Advanced Chemicals (IRCRAC). We particularly address …
Research Center for Refining & Advanced Chemicals (IRCRAC). We particularly address …
Reaction engineering of polyolefins: the role of catalyst supports in ethylene polymerization on metallocene catalysts
M Ahsan Bashir, TFL McKenna - Polymer Reaction Engineering of …, 2018 - Springer
This chapter presents a brief look at different methods for the polymerization of ethylene
using supported metallocene catalysts, then focuses on the effects that the properties of …
using supported metallocene catalysts, then focuses on the effects that the properties of …
Site-averaged kinetics for catalysts on amorphous supports: an importance learning algorithm
Ab initio calculations have greatly advanced our understanding of homogeneous catalysts
and crystalline heterogeneous catalysts. In contrast, amorphous heterogeneous catalysts …
and crystalline heterogeneous catalysts. In contrast, amorphous heterogeneous catalysts …
Silica/MAO/(n-BuCp) 2 ZrCl 2 catalyst: effect of support dehydroxylation temperature on the grafting of MAO and ethylene polymerization
The current study aims to explore the link between the role of silica dehydroxylation
temperature and the catalytic performance of an (n-BuCp) 2ZrCl2 metallocene precursor …
temperature and the catalytic performance of an (n-BuCp) 2ZrCl2 metallocene precursor …
Grafting metal complexes onto amorphous supports: from elementary steps to catalyst site populations via kernel regression
Ab initio computational studies have made tremendous progress in describing the behavior
of molecular (homogeneous) catalysts and crystalline versions of heterogeneous catalysts …
of molecular (homogeneous) catalysts and crystalline versions of heterogeneous catalysts …
Ethylene polymerization over novel organic magnesium based V/Ti bimetallic Ziegler-Natta Catalysts
Y Zhou, R Zhang, H Ren, X He, B Liu, N Zhao… - Journal of Organometallic …, 2020 - Elsevier
A series of novel V/Ti bimetallic polyethylene catalysts were developed successfully through
the introduction of vanadium species into the (SiO 2/MgR 2/MgCl 2)· TiCl x Ziegler-Natta …
the introduction of vanadium species into the (SiO 2/MgR 2/MgCl 2)· TiCl x Ziegler-Natta …
Silica‐supported (nBuCp)2ZrCl2: effect of catalyst active center distribution on ethylene–1‐hexene copolymerization
M Atiqullah, S Anantawaraskul… - Polymer …, 2014 - Wiley Online Library
Metallocenes are a modern innovation in polyolefin catalysis research. Therefore, two
supported metallocene catalysts—silica/MAO/(nBuCp) 2ZrCl2 (Catalyst 1) and …
supported metallocene catalysts—silica/MAO/(nBuCp) 2ZrCl2 (Catalyst 1) and …
Cyclic molecular designed dispersion (CMDD) of Fe2O3 on CeO2 promoted by Au for preferential CO oxidation in hydrogen
A novel cyclic molecular designed dispersion (CMDD) method was employed to uniformly
deposit 0.0–6.5 wt% Fe on CeO 2. The gold catalysts (0.0–3.8 wt%) supported on Fe 2 O 3 …
deposit 0.0–6.5 wt% Fe on CeO 2. The gold catalysts (0.0–3.8 wt%) supported on Fe 2 O 3 …
Effects of a vanadium post-metallocene catalyst-induced polymer backbone inhomogeneity on UV oxidative degradation of the resulting polyethylene film
M Atiqullah, MS Winston, JE Bercaw, I Hussain… - … degradation and stability, 2012 - Elsevier
A Group 5 post-metallocene precatalyst,(ONO) VCl (THF) 2 (ONO= a bis (phenolate)
pyridine LX2 pincer ligand), activated with modified methylaluminoxane (MMAO-3A) …
pyridine LX2 pincer ligand), activated with modified methylaluminoxane (MMAO-3A) …
Influence of MIL-53 on the catalytic performance of metallocene in propylene polymerization
JS Lee, C Manianglung, HI Jeon, YS Ko - Molecular Catalysis, 2025 - Elsevier
In this study, we investigate the application of metal-organic frameworks (MOFs) as a
support for metallocene catalysts in the polymerization of propylene. MOFs such as MIL-53 …
support for metallocene catalysts in the polymerization of propylene. MOFs such as MIL-53 …