Recent developments in and perspectives on three-coordinate boron materials: a bright future

L Ji, S Griesbeck, TB Marder - Chemical Science, 2017 - pubs.rsc.org
The empty pz-orbital of a three-coordinate organoboron compound leads to its electron-
deficient properties, which make it an excellent π-acceptor in conjugated organic …

Advances in the synthesis of organoborane polymers for optical, electronic, and sensory applications

F Jäkle - Chemical reviews, 2010 - ACS Publications
The past decade has witnessed renewed interest and numerous unexpected discoveries in
the area of main group organometallic chemistry. Unusual bonding modes have been …

Applications of three-coordinate organoboron compounds and polymers in optoelectronics

CD Entwistle, TB Marder - Chemistry of materials, 2004 - ACS Publications
Three-coordinate boron, with its vacant p-orbital, is a useful π-acceptor in conjugated
organic molecules. These materials have interesting linear, as well as first-and second-order …

Impact of donor− acceptor geometry and metal chelation on photophysical properties and applications of triarylboranes

ZM Hudson, S Wang - Accounts of chemical research, 2009 - ACS Publications
Three-coordinate organoboron compounds have recently found a wide range of
applications in materials chemistry as nonlinear optical materials, chemical sensors, and …

Designs of functional π-electron materials based on the characteristic features of boron

A Wakamiya, S Yamaguchi - Bulletin of the Chemical Society of …, 2015 - academic.oup.com
Boron, a group 13 element, has several characteristic structural and electronic features: 1)
trivalent boron compounds usually adopt a trigonal planar geometry; 2) due to the presence …

Site-selective Suzuki–Miyaura coupling of heteroaryl halides–understanding the trends for pharmaceutically important classes

J Almond-Thynne, DC Blakemore, DC Pryde… - Chemical …, 2017 - pubs.rsc.org
Suzuki–Miyaura cross-coupling reactions of heteroaryl polyhalides with aryl boronates are
surveyed. Drawing on data from literature sources as well as bespoke searches of Pfizer's …

Boron as a key component for new π-electron materials

S Yamaguchi, A Wakamiya - Pure and applied chemistry, 2006 - degruyter.com
For the molecular design of new π-electron materials, the incorporation of main group
elements into the π-conjugated frameworks is a powerful approach to modifying the nature …

[PDF][PDF] 3-Boryl-2, 2′-bithiophene as a versatile core skeleton for full-color highly emissive organic solids

A Wakamiya, K Mori, S Yamaguchi - Angew. Chem. Int. Ed, 2007 - Citeseer
Supporting Information Page 1 Supporting Information © Wiley-VCH 2007 69451 Weinheim,
Germany Page 2 S1 3-Boryl-2,2’-Bithiophene as a Versatile Core Skeleton for Full-Color …

Luminescent triarylborane-functionalized polystyrene: synthesis, photophysical characterization, and anion-binding studies

K Parab, K Venkatasubbaiah… - Journal of the American …, 2006 - ACS Publications
A new class of highly fluorescent triarylborane polymers has been prepared from
trimethylsilyl-substituted polystyrene via a modular approach that involves selective polymer …

Highly emissive organic solids containing 2, 5-diboryl-1, 4-phenylene unit

CH Zhao, A Wakamiya, Y Inukai… - Journal of the American …, 2006 - ACS Publications
We disclosed a series of π-conjugated systems containing 2, 5-bis (dimesitylboryl)-1, 4-
phenylene as the core unit and electron-donating amino groups at the terminal positions …