Transition-metal-catalyzed reactions have been studied since the very beginning of the past
century and represent a great success in organic chemistry, along with the birth and growth …

Transition-metal-catalyzed decarbonylation via carbon–carbon bond cleavage is an
essential synthetic methodology. Given the ubiquity of carbonyl compounds, the selective …

Fluorinated organic compounds increasingly gain importance in numerous areas of
chemistry and everyday life. Building blocks which contain fluorinated entities are of high …

The gem-difluoroalkenes and related compounds have gained much attention from the
organic synthetic community due to their widespread applications as versatile fluorinated …

Partially fluorinated alkanes, arenes, and alkenes can be transformed by a variety of
transition metal and lanthanide systems. Although the C–H bond is weaker than the C–F …

Much progress has been made in the development of methods to both create compounds
that contain C− F bonds and to functionalize C− F bonds. As such, C− F bonds are becoming …

Fluorinated organoboranes serve as versatile synthetic precursors for the preparation of
value‐added fluorinated organic compounds. Recent progress has been mainly focused on …

The chemistry of heterocyclic compounds has traditionally been and remains a bright area of
chemical science in Russia. This is due to the fact that many heterocycles find the widest …

The activation and functionalization of carbon–fluorine bonds can be considered as a major
challenge in organometallic chemistry. The growing demand for means to introduce fluorine …

In this Account, we describe the transition metal-mediated cleavage of C− F and C− H bonds
in fluoroaromatic and fluoroheteroaromatic molecules. The simplest reactions of …