Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Recent advances in the routes and catalysts for ethanol synthesis from syngas

G Liu, G Yang, X Peng, J Wu, N Tsubaki - Chemical Society Reviews, 2022 - pubs.rsc.org
Ethanol, as one of the important bulk chemicals, is widely used in modern society. It can be
produced by fermentation of sugar, petroleum refining, or conversion of syngas (CO/H2) …

Ambient-pressure synthesis of ethylene glycol catalyzed by C60-buffered Cu/SiO2

J Zheng, L Huang, CH Cui, ZC Chen, XF Liu, X Duan… - Science, 2022 - science.org
Bulk chemicals such as ethylene glycol (EG) can be industrially synthesized from either
ethylene or syngas, but the latter undergoes a bottleneck reaction and requires high …

Status and prospects in higher alcohols synthesis from syngas

HT Luk, C Mondelli, DC Ferré, JA Stewart… - Chemical Society …, 2017 - pubs.rsc.org
Higher alcohols are important compounds with widespread applications in the chemical,
pharmaceutical and energy sectors. Currently, they are mainly produced by sugar …

Crystal plane effect of ceria on supported copper oxide cluster catalyst for CO oxidation: Importance of metal–support interaction

WW Wang, WZ Yu, PP Du, H Xu, Z Jin, R Si, C Ma… - ACS …, 2017 - ACS Publications
Copper–ceria as one of the very active catalysts for oxidation reactions has been widely
investigated in heterogeneous catalysis. In this work, copper oxide (1 wt% Cu loading) …

Selectivity Control in the Direct CO Esterification over Pd@ UiO‐66: The Pd Location Matters

S Hu, C Xie, YP Xu, X Chen, ML Gao… - Angewandte …, 2023 - Wiley Online Library
The selectivity control of Pd nanoparticles (NPs) in the direct CO esterification with methyl
nitrite toward dimethyl oxalate (DMO) or dimethyl carbonate (DMC) remains a grand …

Nanocatalysis: size-and shape-dependent chemisorption and catalytic reactivity

BR Cuenya, F Behafarid - Surface Science Reports, 2015 - Elsevier
In recent years, the field of catalysis has experienced an astonishing transformation, driven
in part by more demanding environmental standards and critical societal and industrial …

ZrO2-x modified Cu nanocatalysts with synergistic catalysis towards carbon-oxygen bond hydrogenation

G Cui, X Zhang, H Wang, Z Li, W Wang, Q Yu… - Applied Catalysis B …, 2021 - Elsevier
Carbon-oxygen bond hydrogenation serves as a versatile fundamental reaction extensively
applied in chemicals synthesis, but rational design of heterogeneous catalysts with …

[HTML][HTML] Palladium based nanomaterials for enhanced hydrogen spillover and storage

SK Konda, A Chen - Materials Today, 2016 - Elsevier
Hydrogen storage remains one of the most challenging prerequisites to overcome toward
the realization of a hydrogen based economy. The use of hydrogen as an energy carrier for …

Roadmap to the sustainable synthesis of polymers: From the perspective of CO2 upcycling

K Sadeghi, Y Jeon, J Seo - Progress in Materials Science, 2023 - Elsevier
The demand for virgin polymers is constantly increasing owing to the desired performance
and low recycling rates of polymers; however, this exacerbates significant plastic-industry …